QA Part II Flashcards
What sort of precipitates dissolve in excess NaOH?
Amphoteric precipitates.
What precipitates dissolve in excess aq ammonia?
Zinc and copper (II)
What ions do not form a ppt in NaOH and aq. ammonia respectively?
NaOH: NH4+ (ammonium). Produces ammonia gas upon heating.
NH3: NH4+ (ammonium) and Ca2+ (Calcium).
How do we differentiate Lead(II) ion from the other amphoteric ions?
Lead(II) chloride and lead(II) sulfate are insoluble (white in colour), so is lead(II) iodide (yellow)
How do we differentiate aluminium ion from the other amphoteric ions?
You have to test for the other two ions. If both tests are negative, you have an aluminium ion.
How do you differentiate zinc ion from other amphoteric ions?
Use aqueous ammonia. If it dissolves in excess NH3 it is FUNNNY! WHEN THE IMPOSTOr I UsUS!
How do we test for carbonate anion? What is the result?
Add dilute hydrochloric/nitric acid. Bubble the gas
produced into limewater.
Effervescence is observed. Gas produced from the reaction will form white precipitate when it reacts with limewater.
How do we test for nitrate anion?
Add dilute sodium hydroxide, then add a
piece of aluminium foil and warm. Test the gas produced (ammonium gas) with a piece of moist
red litmus paper. The moist red litmus paper will turn blue.
How do we test for sulfate anion?
Add dilute nitric acid, and then aq. barium nitrate (or acidified barium nitrate). White ppt of barium sulfate will form.
How do we test for chloride anion?
Add dilute nitric acid to the solution and then add aqueous silver nitrate. White ppt. of silver chloride will form.
How do we test for iodide anion?
Add dilute nitric acid to the solution then add aq. silver nitrate –> yellow ppt. of silver iodide is formed.
Why do we add dilute nitric acid first in tests for sulfate, chloride and iodide ions?
Dilute nitric acid is is added first to react with any carbonate ions or hydroxide ions present. This is to prevent false positive results as carbonate ions also form precipitates with the reagents.
What three compounds can thermal decomposition occur in?
Hydroxides, carbonates, and nitrates.
What is thermal decomposition of a compound?
Breaking down a compound by heat alone. N.B. Thermal decomposition is not combustion as combustion requires oxygen.
What hydroxides does thermal decomposition occur in? What are their products?
All hydroxides except Group I hydroxides. Water vapour is evolved (e.g. Ca(OH)2 –> CaO + H2O)