Chemical Calculations Flashcards

1
Q

What are the two sorts of relative mass?

A

Relative atomic mass (Ar) and relative molecular mass (Mr)

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2
Q

What is relative atomic mass?

A

The average mass of one atom of an element as compared with 1/12 the mass of a carbon-12 isotope.

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3
Q

What is relative molecular mass?

A

The average mass of one molecule of a substance, as compared with 1/12 the mass of a carbon-12 isotope. Mr is found by adding the Ar of the atoms in the compound together.

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4
Q

What is the mole?

A

The mole is a quantifier measure of atoms.

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5
Q

How many atoms are in a mole?

A

Avogadro’s constant: 6 × 10^23. There are 6 × 10^23 atoms in one mole.

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6
Q

How can we find mass from moles?

A

Mass = number of moles × relative mass

No. of moles = mass ÷ relative mass

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7
Q

What is mole ratio and how do we determine mole ratio?

A

Mole ratio is just the idea of “how much of A will react with how much of B”, and is determined using the numbers beside the reactants in a chemical eq.

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8
Q

When you are given data in a question, what is the first step to do?

A

CALCULATE THE NUMBER OF MOLES, THEN MOLE RATIO.

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9
Q

Cubic decimetre (dm3) is often used as the unit of volume in chemistry. What is 1 dm3 equal to in litres, m3, and cm3?

A

1 dm3 = 1 litre = 0.001 m3 = 1000 cm3

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10
Q

What units are used in calculating mass and volume respectively?

A

Grams (g) for mass, cubic decimetres (dm3) for volume.

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11
Q

What is aqueous concentration?

A

It refers to the amount of chemical per unit volume of water. It is only used for aqueous solutions.

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12
Q

How do we find molar concentration and mass concentration respectively?

A
Molar concentration (M) – mol / dm3
Mass concentration – g / dm3

Molar concentration = Number of moles / Volume
Mass concentration = Mass (grams) / Volume

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13
Q

What is the principle of the volume of gases?

A

One mole of any gas occupies a volume of 24 dm3 at a temperature of 25 °C and pressure of 1 atm.

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14
Q

What is the relation between the ratio of the volume of gases to their mole ratio?

A

Ratio of the volume of gases = equivalent to its mole ratio. At room temperature and pressure, 1 mole of any gas would occupy 24 dm3.

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15
Q

What are limiting and excess reagents?

A

In chemical reactions, there is often a reactant leftover (excess reactant) while another is completely used (limiting reactant).

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16
Q

How do we write out the answer for limiting and excess reagents?

A

“[number] mol of [substance] would require [number 2] mol of [substance 2] for a complete reaction. However, there is insufficient [substance 2] / leftover [substance 2] after the reaction. Hence, [substance 1 or 2] is limiting.]”

17
Q

What is percentage mass? How is it calculated?

A

The the mass of a component of a substance in relation to its total mass.

Percentage mass = relative mass of component / relative mass of entire substance × 100%

18
Q

What is percentage yield? How is percentage yield calculated?

A

Percentage yield is the mass of a component of a substance in relation to its total mass.

Percentage yield = average yield of experiment / calculated yield × 100%

19
Q

Why do we calculate percentage yield?

A

In an experiment, the actual measurement you record will not be the same as the calculated, theoretical yield. This is because there would be impurities in the reagents.

20
Q

What is percentage purity? How is it calculated?

A

Percentage purity calculates the purity of an impure ore or mineral. It is the mass of an actual chemical in relation to the total mass.

Percentage purity = real mass of chemical / total mass, including impurities × 100%

21
Q

How might we obtain the real mass of a chemical?

A

The number of moles of a product can be traced back to the number of moles of the reactant.

22
Q

What is empirical formula?

A

Empirical formula reflects the correct ratio between the various elements in simplest form. For example, C6H12O6 can be expressed as CH2O in an empirical formula.

23
Q

How do we find empirical formula?

A

Step 1: State the mass ratio of elements.
Step 2: Divide by relative atomic mass to get the mole ratio of the constituent atoms.
Step 3: Divide the ratio by the smallest mole.
Step 4: The numbers in the ratio you get are used for your empirical formula.
Step 5: Multiply the ratio to get whole numbers if there are decimals.

24
Q

How do we find molecular formulae from empirical formulae?

A

Step 1: Calculate Mr of empirical formula.
Step 2: Divide given Mr by the Mr previously calculated.
Step 3: Multiply the empirical formula by your solution.