Provisional Restorative Materials (Johnston) Flashcards

0
Q

What are three advantages of resin based restorative materials?

A
  1. Relative ease of formation
  2. Translucency
  3. Thermally and electrically insulating
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1
Q

What are four properties of provisional restorative materials?

A
  1. Ease of formation
  2. Promotes oral health
  3. Esthetic appearance
  4. Stable and durable
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2
Q

What are five disadvantages of resin based restorative materials?

A
  1. Exoteric reaction
  2. Polymerization shrinkage
  3. Variable polymerization efficiency
  4. High coefficient of thermal expansion on heating
  5. Low toughness
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3
Q

What are the two categories of polymers?

A

Thermoplastic: no cross linking, reversibly controlled by temp
Thermoset: involves irreversible cross linking

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4
Q

What are two mechanisms of polymerization or setting?

A
  1. Addition polymerization releases no by products

2. Condensation polymerization results in a by product

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5
Q

What is the most exclusive polymeration method for current dental resins?

A

Free radical polymerizations

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6
Q

What are physical phenomena during free radical polymerization?

A
  1. Final properties increased
  2. Material heats up
  3. Volumetric contraction
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7
Q

What are the four chemical stages of polymerization?

A
  1. Activation of initiator
  2. Activation of monomer
  3. Polymer growth
  4. Termination
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8
Q

What are Some properties of activation of initiator?

A
Highly efficient
Is uniform
Large working time
Mixing of initiator and monomer
Needs hearing equipment
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9
Q

What does excessive heat cause?

A

Porosity

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10
Q

What are the three steps in the activation of initiator?

A
  1. Heat activation
  2. Chemical activation
  3. Light activation
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11
Q

What does cross linking do to a material?

A

Cross linking makes the material more durable and resists staining

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12
Q

What happens chemically in the activation of monomer?

A

Free radical + monomer-> active monomer

Change of double bond to two single bonds release heat

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13
Q

Explain the growth of polymer step

A
  • Active polymer spontaneously combines w more monomer
  • Heat of reaction heats material
  • Increases density
  • cross linking between two growing polymers
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14
Q

What are characteristics of the greater the size of a methacrylate monomer?

A
  • less polymerization shrinkage
  • less heat of reaction
  • lower mechanical properties
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15
Q

What occurs in the termination step?

A
  • two active polymers can combine
  • free radical transfer causes polymer to stop growing
  • contaminants
16
Q

T or f: more filler the stronger the material

A

True

17
Q

T or f: most methacrylates are translucent

A

True