Provisional Restorative Materials (Johnston) Flashcards
What are three advantages of resin based restorative materials?
- Relative ease of formation
- Translucency
- Thermally and electrically insulating
What are four properties of provisional restorative materials?
- Ease of formation
- Promotes oral health
- Esthetic appearance
- Stable and durable
What are five disadvantages of resin based restorative materials?
- Exoteric reaction
- Polymerization shrinkage
- Variable polymerization efficiency
- High coefficient of thermal expansion on heating
- Low toughness
What are the two categories of polymers?
Thermoplastic: no cross linking, reversibly controlled by temp
Thermoset: involves irreversible cross linking
What are two mechanisms of polymerization or setting?
- Addition polymerization releases no by products
2. Condensation polymerization results in a by product
What is the most exclusive polymeration method for current dental resins?
Free radical polymerizations
What are physical phenomena during free radical polymerization?
- Final properties increased
- Material heats up
- Volumetric contraction
What are the four chemical stages of polymerization?
- Activation of initiator
- Activation of monomer
- Polymer growth
- Termination
What are Some properties of activation of initiator?
Highly efficient Is uniform Large working time Mixing of initiator and monomer Needs hearing equipment
What does excessive heat cause?
Porosity
What are the three steps in the activation of initiator?
- Heat activation
- Chemical activation
- Light activation
What does cross linking do to a material?
Cross linking makes the material more durable and resists staining
What happens chemically in the activation of monomer?
Free radical + monomer-> active monomer
Change of double bond to two single bonds release heat
Explain the growth of polymer step
- Active polymer spontaneously combines w more monomer
- Heat of reaction heats material
- Increases density
- cross linking between two growing polymers
What are characteristics of the greater the size of a methacrylate monomer?
- less polymerization shrinkage
- less heat of reaction
- lower mechanical properties