Properties of Functional Groups Flashcards

1
Q

True or False; alcohols are polar

A

True

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2
Q

True or False; alcohols have low boiling points

A

False (They have higher boiling points than hydrocarbons
of similar molar mass)

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3
Q

True or False; the boiling point of alcohols increases as the length of carbon chain
and OH groups increase

A

True

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4
Q

Alcohols with one to four carbons are _____ in water.

A

Soluble

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5
Q

Alcohols with five to six carbons are _____ in water.

A

Moderately soluble

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6
Q

Alcohols with seven carbons or more are _____ in water.

A

Nearly insoluble

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7
Q

True or False; Diols and triols are more water
soluble than alcohols with only a
single hydroxyl group

A

True

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8
Q

True or False; All functional groups are polar except for Thiols

A

True

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9
Q

True or False; Ethers have lower boiling points than alcohols of
similar molar mass due to lack of hydrogen
bonding.

A

True

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10
Q

True or False; Ethers have lower boiling point than alkanes

A

False

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11
Q

True or False; Ethers are less soluble in water and more soluble in organic solvents

A

True

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12
Q

True or False; Thiols have high solubility in water

A

False (They have lower solubility)

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13
Q

True or False; Ethers have lower boiling points than alkanes of similar molar mass.

A

False (They have higher)

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14
Q

True or False; Solubility falls off dramatically as the carbon content of the carboxylic acid increases.

A

True

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15
Q

True or False; Carboxylic acids have significantly higher
boiling points than other types of organic
compounds of comparable molecular
weight

A

True

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16
Q

True or False; Boiling point of esters is higher than alcohol and carboxylic acid.

A

False (It is lower)

17
Q

True or False; Aldehydes boil at higher temperatures than alcohol.

A

False eyyy (They boil at lower temperatures)

18
Q

True or False; Ketones boil at lower temperatures than alcohol of similar molar mass because of weaker forces.

A

True

19
Q

True or False; In amines, boiling point decreases in the absence of hydrogens. The boiling point is highest in primary amines.

A

Korique

20
Q

True or False; Amines boil at higher boiling points than alkanes and ethers.

A

Trueeee

21
Q

True or False; Amides boil at lower temperature than amine and other hydrocarbon.

A

False (They boil at higher)

22
Q

True or False; generally, water solubility decreases as the length of the hydrocarbon portion increases

A

True

23
Q

Only how many carbons in aldehydes can guarantee solubility in water?

A

Five or fewer

24
Q

Which functional groups generally have low solubility in water?

A

Ethers and thiols

24
Q

Which functional groups generally have low solubility in water?

A

Ethers and thiols

25
Q

Which part of the structure of functional groups are water-fearing or hydrophobic?

A

Hydrocarbon part