Properties of Carboxylic Acids Flashcards
what types of bonds are in carboxylic acids?
- hydrogen bonding between the C=O and O-H bonds
- these bonds are polar so can form hydrogen bonds with water molecules
what is the limit for the number of carbon atoms in a carboxylic acid until it’s insoluble in water?
- carboxylic acids with up to 4 carbon atoms are soluble in water
what happens to the solubility of carboxylic acids as the number of carbon atoms increases?
- as the number of carbon atoms increases, the solubility decreases the non-polar carbon chain has a greater effect on the overall polarity of the molecule (London forces are stronger than hydrogen bonding)
why does solubility of carboxylic acids in non polar solvents decrease as the number of carbon atoms increase?
- non-polar carbon chain has a greater effect on the overall polarity of the molecule
what is the state of dicarboxylic acids?
- solids at room temperature, and they dissolve readily in water
as the number of carbon atoms increases what bond has more of an effect?
- London forces are stronger than hydrogen bonds
what type of acids are carboxylic acids?
- weak acids
- partially dissociates in aqueous solutions
what are the types of reactions that carboxylic acids can take part in?
- redox reactions with metals
- neutralisation reactions with bases (alkalis, metal oxides and carbonates)
what happens when carboxylic acids react in redox and neutralisation reaction?
- carboxylic acids form carboxylate salts
what is formed when carboxylic acids react with metals in a redox reaction?
- hydrogen gas is formed and the carboxylate salt
what happens during the reaction of carboxylic acids and metals in redox reactions?(observations)
- metal disappears
- effervescence
what type of acids are carboxylic acids?
weak acids, so partially dissociate
what are the bases that carboxylic acids react with?
- metal oxides
- alkalis
- carbonates
what is formed when carboxylic acids react with metal oxides?
- salt (carboxylate)
- water
what is formed when carboxylic acids react with alkalis?
- carboxylate salt
- water