Properties Of Carboxylic Acid And Esters Flashcards
What is carboxylic acid and esters structure?
- They both contain a carbonyl group, however carboxylic acids also have a attached hydroxyl group, on the other hand the H in the OH is replaced with an alkyl group
What are the properties of carboxylic acids?
- behave as weak acids, only slightly ionized in water
- they are soluble up to 4 Carbons
- sour bitter, unpleasant odor, only low molecular weight carboxylic acids have an odor
What is the properties & reactions of esters
1) derived from carboxylic acids by replacing the H with and aryl or alkyl group via their reactions with alcohols (R-COOH +
R’-OH = R-COOR’ + H2O)
2) esters can be hydrolyzed (the reaction in water catalyzed by an acid or base “H+”) producing a carboxylic acid and alcohol (R-COOR’ + H2O + H+ = R-COOH + R’-OH) in water hydrolysis, and sodium salt and alcohol (R-COOR’ + NaOH = R-COO(-)Na+ + R’-OH) in basic hydrolysis
3) it has a nice odor used in food industry as flavoring and fragrances
What are the reactions of carboxylic acids?
1) they react with bases to form carboxylic acid salts & water (CH3COOH + NaOH = CH3COO-Na+ + H2O)
2) they react with alcohol to form esters (R-COOH + R’-OH = R-COOR’ + H2O)