properties of alkanes Flashcards

1
Q

what is the alkanes general formula

A

CnH2n+2

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2
Q

how is a sigma bond formed in alkanes

A

the overlap of orbitals directly between the bonding atoms

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3
Q

how do sigma bonds rotate

A

freely

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4
Q

what is the shape and bond angle of alkanes

A

each carbon is surrounded by 4 bonded pairs of electrons. these all repel as far as possible, resulting in a tetrahedral shape and a bond angle of 109.5

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5
Q

what is the trend in boiling points of straight chain alkanes and why

A

as carbon chain length increases boiling point increases
as there are: more electrons, more points of contact between atoms, strength of London forces between molecules increases and more energy is needed to break the IMFs

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