Properties Flashcards

1
Q

What is the definition of polarity?

A

Polarity is a separation of charge which tells us whether a molecule will dissolve in water or boil at a certain temperature.

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2
Q

What is electronegativity?

A

The bonding attraction of atoms.

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3
Q

Which atoms have the highest electronegativity?

A

The top right of the periodic table.

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4
Q

Which atoms have the lowest electronegativity?

A

The bottom left of the periodic table.

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5
Q

What are the requirements to make a non-polar covalent bond in terms of atoms?

A

There needs to be no real charge difference across the molecule. OR atoms need to be the same or symmetrical.

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6
Q

Why do non-polar covalent bonds have no separation of charge?

A

They are similar or have the same electronegativity’s.

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7
Q

What are the requirements to form a polar covalent bond in terms of atoms?

A

There needs to be a difference in electronegativity between the atoms. (unsymmetrical)

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8
Q

Why are alkanes, alkenes and alkynes non-polar?

A

They have a symmetrical shape.

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9
Q

Are haloalkanes polar or non-polar?

A

They are polar when the molecule is small with a strong haloalkanes, but they are non-polar most the time as the long carbon chain is too strong and balances out.

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10
Q

Which organic molecules are always considered polar?

A

Haloalkanes - when small
Compounds with oxygen - when small
Compounds with nitrogen
Carboxylic acids.

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11
Q

How are solids converted to liquids and how is liquid converted to gas.

A

All substances exist as gases liquids and solids at different temperatures and pressures. By increasing the temperature solids break down into liquid. This is the same for liquid to gas.

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12
Q

What are the 3 intermolecular forces and their relative strength?

A
  1. Instantaneous dipole-dipole forces between all molecules (WEAK)
  2. Permanent dipole-dipole forces in polar molecules (MED)
  3. Hydrogen bonding between molecules which has a hydrogen bonded to a highly electronegative atom. (STRONG)
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13
Q

What is the name of the attractive force that holds molecules together?

A

Intermolecular forces

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14
Q

Why do alcohols have higher melting/boiling points than alkanes, alkenes and alkynes?

A

They are held together by stronger forces.

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15
Q

Do straight or branched chains have higher melting/boiling points and why?

A

Straight chains. The straighter the chain the closer molecules are together therefore greater forces exist.

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16
Q

What does solubility mean?

A

How likely is something to dissolve in something else.

17
Q

What are the rules of solubility?

A

Like dissolves in like.

18
Q

Why are alkanes, alkenes and alkynes insoluble in water?

A

They are all non-polar molecules. Water is polar. Like dissolves in like therefore alkanes, alkenes and alkynes are insoluble.

19
Q

Why are small carboxylic acids and amines soluble in water but large alcohols are insoluble in water.

A

When a molecule is bigger its non-polar therefore insoluble in water. (like dissolves in like)