Products From Crude Oil Flashcards

1
Q

What are alkenes

A

Another family of hydrocarbons that contain a carbon carbon double bond

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2
Q

What do double bond involve

A

Sharing two pairs of electrons

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3
Q

What does unsaturated mean

A

Contains at least one double bond

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4
Q

What is the general formula for alkenes

A

C(n)H(2n)

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5
Q

Why is there not a methene

A

There is only one carbon atom is methane. There needs to be a carbon carbon double bond for for there to be an alkene

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6
Q

How many bonds does carbon need to make to get a full outer shell

A

4

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7
Q

What can alkenes also undergo just like alkanes

A

Combustion

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8
Q

What is cracking

A

A process which breaks down large hydrocarbon molecules into smaller, more useful molecules

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9
Q

Why do we need to crack

A

Some of the heavier fractions from fractional distillation are not useful as they are made of large molecules and are poor fuels

The smaller hydrocarbons are more useful

Unfortunately there is a high supply and low demand for large hydrocarbons and a low supply and a high demand for small hydrocarbons

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10
Q

How does cracking work

A

It involves heating the hydrocarbon strongly so it turns into a gas and passes through a hot catalyst

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11
Q

What type of reaction is cracking and what does it mean

A

Thermal decomposition reaction - breaking down a substance using heat

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12
Q

What are the two types of products from cracking

A

Smaller alkane that is a more useful fuel

Alkenes

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13
Q

What is the test for alkenes and result and explanation

A

Bromine water (orange)

Alkene present - turns colourless
Alkane present - stays orange

Explanation - alkenes have double bond so reacts as the double bond breaks

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14
Q

Monomer definition

A

A small molecule that can combine wth similar molecules to form a long molecule called a polymer

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15
Q

Polymer definition

A

Very long molecules made of smaller molecules called monomer

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16
Q

What is addition polymerisation

A

The process where monomers join together by single bonds to form 1 large polymer molecule

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17
Q

What is an example of a monomer

A

Alkenes

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18
Q

What happens during addition polymerisation

A

Under high pressures and temperatures double bonds in the monomer molecules break to form a single bond

Millions of monomers join together by single bonds to form one long polymer

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19
Q

What is the use of polyethene and what is the displayed formula

A

Plastic bags, milk cartons, shampoo bottles

n C=C

[—–C-C—– ] n

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20
Q

What is the use of polypropene

A

Rope, milk crates

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21
Q

Why does polystyrene and polypropene have different properties

A

They are made from different polymers and before that monomer so have different properties

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22
Q

What are the two types of polyethene

A

Low density and high density

23
Q

How is low density polyethene made

A

Under high pressures and a trace of oxygen

24
Q

Why is low density polyethene low density

A

The polymer chains have random branches so are unable to patch closely together

25
How is high density polyethene formed
Using a catalyst at 50degreesC, slightly high pressure
26
Why is high density polyethene high density
The polymer chains are straighter and without branches so are able to pack closely together
27
Why do plastics soften easily when heated
There are weak intermolecular forces between the molecules as there are no covalent bonds (cross links) so the plastic can soften easily when heated
28
How can we classify polymers
By looking at what happens when they get heated
29
What are thermosoftening polymers
Polymers which soften easily when heated and reset when cooled. They are made of polymer chains that are tangled together and can easily separate as they have weak intermolecular forces between them
30
What are thermosetting polymers
Polymers that do not melt when heated a they have strong covalent bonds between. The polymer chains called cross links
31
Properties of thermosetting polymers (2)
Cross links don't break when heated Rigid
32
Properties of thermosoftening polymers
Weak intermolecular forces that break when heated Melts easily but rehardened again when cooled so can be remoulded
33
Why are plastic bags made out of thermosoftening polymers (2)
Flexible Tensile strength (can stretch)
34
Why are thermosetting polymers used for pan handles
Don't melt under intense heat during cooking Rigid
35
Why are waste plastics a problem
They take up space in landfill sites and take a long time to break down. Wildlife might also get trapped in the waste plastic and die
36
What are biodegradable polymers
These plastics rot away in soil and are broken down by microorganisms
37
What raw material is good to make biodegradable stuff
Plant
38
What is the monomer of polylacticacid
Lactic acid
39
How can non-biodegradable polymers be made to decompose more quickly
Use fermented cornstarch to make plastic material
40
What are the problems with using cornstarch to make polymers (2)
Crops for food are being used for plastics (famine + increases food prices) Destruction of habitats
41
What is the problem with using degradable polymers that break down in light
Most of the plastics won't decompose as they are buried in the landfill site
42
What does corn starch speed up decomposition
Microorganisms feed on the corn starch in the plastic
43
What are the two processes for making ethanol
Fermentation of sugar | Hydration of ethene
44
Advantages of using the method fermentation of sugar to produce ethanol (3)
Uses renewable plant material Carbon neutral Cheap conditions- anaerobic respiration in yeast and warm temperatures
45
Advantages of using the method of hydration of ethene to produce ethanol (4)
Continuous process Fast reaction 100% pure product first time High yield
46
Disadvantages for using fermentation of sugar for producing ethanol (5)
``` Slow reaction Batch process Not 100% pure product first time Low yield Uses land to grow sugar cane (famine + increase food prices) ```
47
Disadvantages for using hydration of ethene for producing ethanol (3)
Uses finite fossil fuels Not carbon neutral High temperatures and pressures
48
How is the chemical structure of an alkene different to an alkane
Alkenes have double bonds
49
What needs to reacts with ethene to produce ethanol
Steam
50
Two differences between cracking and polymerisation
Long chains turn to short chains in cracking and short monomers join to make a long polymer Cracking had more than one product whereas polymerisation has one
51
Why is cracking an important process in the oil industry
The supply for shorter hydrocarbon chains is low but the demand is high. The supply for longer hydrocarbon chains is high but the demand is low. Cracking will satisfy the demand
52
What is the process called that separates a mixture with different boiling points
Fractional distillation
53
Why is it important to keep control variables constant
So that only the independent variable ins allowed to have an affect on the dependent variable