Cram Flashcards
Flame test colours (6)
Li+ crimson
Na+ yellow
K+ lilac
Ca2+ brick red
Ba2+ apple green
Cu2+ green/ blue
What reacts with metal ions to form coloured precipitates
Colours pls (6)
NaOH
Ca2+ white insoluble in excess NaOH
Mg2+ white insoluble in excess NaOH
Al3+ white soluble
Cu2+ blue
Fe2+ (dirty) green
Fe3+ brown
Test for carbonate
Result
Add an acid
Produces CO2, cloudy limewater
Test for sulphate
Result
Dilute HCL and BaCl2
White insoluble precipitate (BaSO4)
Test for halide ions
Result
Dilute HNO3 and AgNO3
Produces different colour precipitates
Cl- white
Br- cream
I- yellow
3 advantages and 2 disadvantages of instrumental methods of analysis
More accurate and sensitive
Faster
Enables small samples to be analysed
Need to have a skilled/ trained specialist to use it
Very expensive
What does mass spectroscopy show (2)
The relative molecular mass of a compound
Shows the structure by how the sample breaks up as it passes though, the fragmentation pattern can be matched to known compounds
Colours of phenolphthalein indicator
Alkali pink
Acid colourless
How to get mol/dm3 to g/dm3
x Mr
Alcohol to carboxylic acid?
And the other product?
Add an oxidising agent [such as potassium dichromate (VI) solution], H2SO4 catalyst and water bath to alcohol
Water
Sodium + ethanol ->
Sodium ethoxide + hydrogen
Test for carboxylic acid
What does it produce
Add a carbonate (e.g. sodium carbonate)
Carbon dioxide and water
Volatile meaning
Evaporates easily
Making an ester
+ 3 conditions
Alcohol + carboxylic acid
Add CONCENTRATED H2SO4 catalyst
Got water bath
Add NaHCO3 to neutralise acid catalyst
The Haber process
H2 is from methane at high temperatures
N2 is from the air by fractional distillation
Gas stream contains purified H2 and N2
Converter heats the mixture to 450°C and compresses to a pressure of 200atm
Reaction vessel has the gases over an iron catalyst
Separator cools gases
Only ammonia condenses and is removed as a liquid
Unreacted H2 and N2 are recycled back to the reaction vessel