Predicting Products Of Electrolysis Flashcards

1
Q

why cant a solid ionic compound be electrolyised

A

because the ions are in fixed positions and cant move

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2
Q

why can molten ionic compounds be electrolysed

A

because their ions can freely move and therefore conduct electricity

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3
Q

what happens to positive metal ions during electrolysis

A

they are attracted to the negatively charged cathode and reduced

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4
Q

what happens to the negative ions during electrolysis

A

they are attracted to the positively charged anode and oxidised

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5
Q

what are the products from potassium chloride at the anode and cathode if they were to be electrolysed

A
  • the product at the cathode would be the potassium

- the product at the anode would be the chlorine gas

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6
Q

what is the half equation for the reduction of potassium during electrolysis

A

K+ + e- = K

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7
Q

what is the half equation for the oxidisation of chlorine during electrolysis

A

2Cl- = Cl2 + 2e-

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8
Q

what will also be reduced or oxidised during electrolysis apart from the ionic compound

A
  • the hydrogen ions (H+)

- and hydroxide ions (OH-) from the water

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9
Q

what will be produced if the metal is more reactive than the hydrogen ions when they are both attracted to the cathode

A

hydrogen gas will be prodcued

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10
Q

what will be produced is the metal is less reactive than the hydrogen ions when they are both attracted to the cathode

A

a solid layer of the pure metal will be produced

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11
Q

what is produced at the anode if the hydroxide and halide ions are present

A
  • molecules of the halide will be formed in their halogen form
  • such as chlorine being oxidised
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12
Q

what is produced at the anode if only hydroxide ions are present and no halide ions are present

A

oxygen will be formed

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13
Q

how can you predict whether a metal will be more or less reactive than hydrogen

A
  • by looking at the reactivity series

- and paying attention to the atomic radii that the atoms have according to their period

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14
Q

what are the four ions present in potassium chloride solution

A

K+ Cl- H+ OH-

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