Electrolysis Flashcards

1
Q

What does electrolysis loosely translate to

A

splitting up with electricity

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2
Q

what is done in the process of electrolysis

A
  • electric current is passed through an electrolyte
  • ions move towards the electrodes where they react
  • reaction causes compound to decompose
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3
Q

what is an electrolyte with examples

A
  • a molten or dissolved ionic compound that can conduct electricity (what you are electrolysing)
  • the metal and the non-metal (aluminium oxide)
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4
Q

what happens to the positive ions in electrolysis

A

positive ions in the electrolyte move towards the cathode and gain electrons (reduced)

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5
Q

what happens to the negative ions in electrolysis

A

negative ions in the electrolyte move towards the anode and lose electrons (oxidised)

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6
Q

what is a cathode

A

a negative electrode

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7
Q

what is an anode

A

a positive electrode

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8
Q

what does the movement of ions in the electrolyte to electrodes result in

A

the creation of a flow of charge through the electrode

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9
Q

what does the loss or gain of electrons of the ions form and what happens to it

A

the uncharged element which is discharged from the electrolyte

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10
Q

what is an electrode

A

a solid that conducts electricity and is submerged in the electrolyte

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11
Q

why cant an ionic solid be electrolysed but molten ionic compounds can

A
  • ionic solids cant be electrolysed because the ions are in a fixed position so they arent free to move
  • molten ionic compounds can because the ions can move freely and conduct electricity
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12
Q

what happens to positive metal ions in electrolysis, with a symbol equation as an example

A
  • they are reduced to the element at the cathode

- Pb2+ + 2e- = Pb

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13
Q

what happens to negative non-metal ions in electrolysis, with a symbol equation as an example

A
  • they are oxidised to the element at the anode

- 2Br- = Br2 + 2e- (2e- is the loss of the electrons)

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14
Q

if you want to extract a metal but its too reactive to be reduced with carbon, what method would be used

A

electrolysis

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15
Q

what are the ecological issues with electrolysis

A
  • very expensive method of extraction

- lots of energy is needed to melt the ore and produce the required current

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16
Q

what is the most important mnemonic to remember when it comes to electrolysis

A
- OILRIG
Oxidisation
Is (the)
Loss of electrons
Reduction
Is (the)
Gain of electrons
17
Q

in a setup for electrolysis, which side are the cathodes and anodes on and in what direction are the electrons flowing

A
  • cathode is on the left
  • anode is on the right
  • electrons flow into the cathode (the the left)
18
Q

how would you prepare a molten iomci substance to be electrolysed

A
  • put solid ionic substance in a crucible
  • the ionic substance will become the electrolyte
  • heat the crucible wjth a bunsen burner until the solid is molten
  • once solid is molten dip two clean inert electrodes into electrolyte
  • connect electrodes to power supply using wires and clips
19
Q

why should you heat the solid ionic substance with a bunsen burner in a fume cupboard

A

to avoid releasing any toxic fumes into the room

20
Q

what are examples of inert electrodes and why are they inert

A
  • graphite or platinum

- they are inert because they are unreactive

21
Q

how can you check to make sure a current is flowing through the electrodes

A

put an ammeter or a bulb in series with your circuit to check you have set it up correctly