practical Flashcards

1
Q

Observation for ligand replacement for hexaaquacopper ions

A

With ammonia solution - Blue precipitate forms. Excess ammonia dark blue solution forms

With concentrated HCl - blue solution changes to yellow

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2
Q

Recall the aqueous complexes of the following

Cr3+

A

Green

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3
Q

Cr2O7 2-

A

Orange

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4
Q

CrO4 2-

A

Yellow

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5
Q

Mn 2+

A

Pink

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6
Q

Fe 2+

A

Green

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7
Q

Fe 3+

A

Orage

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8
Q

Co 2+

A

Pink

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9
Q

Ni2+

A

Green

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10
Q

Cu 2+

A

Blue

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11
Q

V 2+

A

Violet

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12
Q

V3+

A

Green

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13
Q

VO2+

A

Bue

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14
Q

VO2 +

A

Yellow

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15
Q

For the following give the colour of the complex and if its soluble in excess sodium hydroxide or excess ammonia
Cr3+

A

Green-blue precipitate soluble in excess sodium hydroxide

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16
Q

Mn2+

A

White ppt , turns brown on standing, insoluble

17
Q

Fe2+

A

Green ppt, insoluble

18
Q

Fe3+

A

Brown ppt, insoluble

19
Q

Co2+

A

Blue ppt, soluble in excess ammonia, yellow solution

20
Q

Ni2+

A

Green ppt, soluble in excess ammonia, blue solution

21
Q

Cu2+

A

Blue ppt, soluble in excess ammonia dark blue solution

22
Q

What is observed in the reaction of amino acids with copper (II) sulfate?

A

Solution turns blue black

23
Q

What is the appearance of aspirin?

A

White crystals.