Polymers and fibres Flashcards

1
Q

What are fibres made up of?

A

Polymers

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2
Q

What are polymers?

A

-Large molecules
-Linked monomer units

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3
Q

What are example of polymers?

A

-Vinyl chloride
-Styrene
-Glucose

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4
Q

What is the process of joining polymers together?

A

Polymerisation

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5
Q

What is a natural polymer?

A

Natural fibres
e.g. hemp or cotton, proteins, DNA

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6
Q

What are semi-synthetic polymers

A

Part natural, part man-made
e.g. Rayon fibres and cellophane

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7
Q

What are synthetic polymers?

A

Man-made
e.g. plastics: PVC, polystyrene, PTFE and nylon

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8
Q

What are co-polymers?

A

-Very large molecules
-Different linker monomers
e.g. styrene and 1,3-butadiene

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9
Q

What is a random co-polymer?

A

Monomer units organise themselves in a random fashion

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10
Q

What are alternating co-polymers?

A

monomer units organise themselves in an alternating fashion

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11
Q

What are block co-polymers?

A

Monomer units organise themselves into blocks

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12
Q

What are graft co-polymers?

A

Long chain of a single monomer unit, with branches of other monomer units grafted on

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13
Q

What are branched polymer chains?

A

Main chain with branches/side chains attached

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14
Q

What is an example of a branched polymer chain?

A

Polyethylene, low density = high degree of branching

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15
Q

What does a high degree of branching produce in polymer chains?

A

High flexibility

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16
Q

What are flexible polymers used to produce?

A

Films

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17
Q

What are non-flexible polymers used to produce?

A

Stiffer plastics used in bottles

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18
Q

What is a cross linked polymer chain?

A

Linear chains which are joined together by small vertical chains at random positions along the main chain

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19
Q

What is an example of a cross linked polymer chain?

A

-Poly(isoprene) rubber
-Epoxy resin (glue)

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20
Q

What is a linear polymer chain?

A

Most common
Chains in a linear fashion

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21
Q

What is an example of a linear polymer chain?

A

-PVC
-Polystyrene
-Nylon

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22
Q

What is a dendrimer polymer chain?

A

Only used in specialised polymers, which have specific uses.
Every unit is branched

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23
Q

What does chain growth polymerisation produce?

A

Makes plastics

24
Q

What does cationic polymerisation produce?

A

Bicycle tubes

25
What does anionic polymerisation produce?
Superglue fuming for fingerprints
26
What does step growth polymerisation produce?
Nylon
27
What is step growth polymerisation further classified into?
-Thermoplastic -Thermosetting -Elastomers
28
What is thermoplastic polymerisation?
-High glass temperature -Hard at room temp -Soft when heated e.g. Lego
29
What is thermosetting polymerisation?
-Heated produces extensive 3D linkage -Highly cross linked -Solidifies and can't be reshaped or remoulded
30
What does thermosetting polymerisation produce?
A hard, single, large molecule Inflexible and can crack e.g. Bakelite
31
What is elastomer polymerisation?
-Ability to stretch and return to the original shape due to weak van der whal forces e.g. rubber, tires
32
What are fibres?
-Thin threads of molten polymer extruded through a spinneret -Then cooled and drawn out along the axis of the fibre to give strength
33
What are the classifications of natural fibres?
-Animal -Plant source -Mineral
34
What is cellulose?
-A natural fibre -Large polymer unit made from glucose monomer units
35
What are glucose units in cellulose held together by?
Hydrogen bonds
36
What is a dicot fibre?
Has 2 seed leaves
37
How does cellulose look under the microscope?
-Transparent -Colourless -Curved twisted fibres -Surface striations -Circular cross section
38
What is kapok?
A seed fibre
39
What do kapok fibres look like?
-Smooth -Hollow -Thin walled cylinders -Twisting and sharp bending -Silky like substance
40
What are kapok fibres used for?
A stuffing agent Fibres are brittle and inelastic and can't be spun into fabric
41
What are flax fibres?
-Dicot fibres -Skin fibres -High cellulose conc -Stronger than cotton
42
What are hemp fibres?
-Dicot fibres -Comes from cannabis plant
43
How do hemp fibres appear?
-Colourless -Transparent cylinders -Surface irregularities -Polygonal cross section
44
What do synthetic fibres contain?
One polymer
45
What are bicomponent fibres?
Contains 2 different polymers
46
What are the general characteristics of bicomponent fibres?
-No surface characteristics -Regular and uniform shape -Can't be identified under microscope when comparing 2 fibres
47
What is a nylon?
A step-growth polymer
48
What does nylon consist of?
It's a molecule with an amine group on one end of the molecule and a carboxylic acid one another
49
What is nylon used in?
Carpets Seatbelts
50
What is kevlar?
The strongest synthetic fibre
51
What does kevlar consist of?
monomer units are aramids, due to benzene ring Linked by hydrogen bonds
52
What is kevlar used in?
Bulletproof vests Army uniforms
53
What gives kevlar it's strength?
Network of hydrogen bonds
54
What are semi-synthetic fibres?
Regenerated forms of cellulose
55
What are rayon fibres?
Semi-synthetic fibres extracted from wood or cotton
56