Polymers Flashcards

1
Q

What does polymerisation include?

A

joining of bifunctional monomers with the Elimination of a small molecule such as water

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2
Q

In the formation of condensation polymers where you have two different monomers, how are the monomers normally arrange?

A

alternately

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3
Q

what is the coo functional group?

A

ester group

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4
Q

What is the functional group of a benzene?

A

aromatic

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5
Q

what can functional groups be?

A

cyclical- e.g. cyclical ester

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6
Q

What is the phenyl functional group?

A

benzene with r group

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7
Q

What happens in the formation of polyesters?

A

alcohol only loses H and carboxylic acid looses oH

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8
Q

What do the monomers that make up a polyamide join together by?

A

formation of amide bond

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9
Q

What do amines loose in polymerisation?

A

H

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10
Q

What is the the bond between polyesters?

A

o
II
o—c

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11
Q

Often in practice what are dicarboxyic acids converted to and why?

A

diacylchlorides which are the reacted with a diamine or diol- this is because acylchlorides are more reactive than cooh

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12
Q

How would I draw 2 repeats of a polymer?

A

draw two monomers in one box joined

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13
Q

Where do I draw the. box around for the repeat monomer?

A

when dotted line repeats

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14
Q

What are polypeptides?

A

Another form of polyamides

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15
Q

What are condensation polymers made from?

A

a single bifunctional monomer reacting with another of the same monomer or two monomers with different functional groups reacting together.
During polymerisation a small molecule like water or HCl is normally the by product.

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16
Q

What are condensation monomers generally?

A

biodegradeable through acid or base hydrolysis of the ester or amide
bond

17
Q

When do addition polymers form?

A

when a i bond in an alkene is broken and two new bonds are formed. The polymer forms a long chain of continuous carbon atoms. They are usually made from a single monomer containing a C=C bond

18
Q

What are addition polymers generally not?

A

biodegradeable as withstand hydrolysis