Polymers Flashcards

1
Q

Best polymer properties (3)

A

Cheap, Lightweight, corrosion resistance

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Difference between Engineering polymers and common

A

Improved strength and temp performance

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What are polymers?

A

Repeat units of a molecular unit

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

2 Ways of creating polymers

A

Addition polymerisation, condensation polymerisation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Addition polymerisation what

A

Monomers are joined together with no extra product created

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Condensation Polymerisation

A

To molecules are added together

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Does condensation polymerisation result in an additional product

A

yes a condensate (water, methane)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

How to measure polymer size(2)

A

Molecular weight or degree of polymerisation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

How to calculate degree of polymerisation?

A

number of monomers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Polymer chains- Linear

A

just straight

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Polymer chains- branched, properties

A

like tree, lower density and strength

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Polymer Chains- crosslinked (properties)

A

covalent bonds- increases strength and stiffness

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What is a copolymer?

A

2 or more types of polymer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

grafted copolymer what

A

linear with one monomer and branches of the other sticking out

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Block copolymers what

A

many of one monomer and then many of the other

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Thermoplastics- structure

A

linear/ branched

17
Q

Thermoplastics- tensile properties (4) and why?

A

plastic and ductile, not strong low density cause chains can be pulled apart from each other

18
Q

Thermoplastics- heat?

A

Soften and melt

19
Q

Thermoplastics- crystal

A

mix of amorphous and crystalline

20
Q

Thermoplastics- examples

A

Polyester, polycarbonate, polyethylene

21
Q

Thermoplastics - stress strain curve why weird

A

Stress reduces after elastic region

22
Q

Why does stress strain curve weird

A

Cause the chains slide rotate disentangle and become aligned with stress direction

23
Q

Thermoplastics temperature dependence

A

Can be glassy leathery or viscous depending on temp

24
Q

Thermoplastics- creep- describe

A

under constant load sample gradually gets longer

25
Q

Thermoplastics - relaxation describe

A

under constant strain leads to stress reaction- exponential- depending on temp

26
Q

Thermosetting- chains?

A

Cross-linked

27
Q

Thermosetting- heat?

A

do no soften

28
Q

Thermosetting- properties (3)

A

Harder, more brittle and more stable

29
Q

Elastomers- chains

A

Crosslinked but specially

30
Q

Elastomers- deformation

A

no plastic deformation but still has viscoelastic relaxation

31
Q

Thermoplastics - blow moulding

A

using air to get into shape

32
Q

Thermoplastics- calendaring

A

Like making pasta

33
Q

Thermoplastics- thermoprocessing

A

using a vacuum to suck it to the right bits

34
Q

Thermoplastics-injection moulding

A

Injecting plastics into mould

35
Q

Thermosets- processing general

A

must be processed and a liquid before cross-linking

36
Q

Thermosets- compression moulding

A

using hot dies to shape and start crosslinking

37
Q

Thermosets- transfer moulding

A

put in mould and then it will polymerize through heat

38
Q

Are thermoplastics recyclable

A

yes but not easy as have to be pure and get rid of extras

39
Q

Are thermosets recyclable

A

no