Polymeric Materials Flashcards

1
Q

What are polymers

A

– Very large molecules
– low density, light weight materials
– may be extremely flexible
– synthetic and natural materials

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2
Q

What type of bond to polymers have

A
Covalent Bond
• electrons are shared between adjacent atoms, each contributing at least one electron
• shared electrons belong to both atoms
• directional bond means resulting
molecules have specific shapes
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3
Q

Polymer Definition

A

A long 1D chain molecule of covalently bonded repeat units

Or a 3D network of covalently bonded repeat units

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4
Q

Advantages of Polymer Characteristics

A

Easy Processing, High Ductility, Light Products, Thermal Insulators, Electrical Insulators, High Corrosion Resistance

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5
Q

What atoms is a polymer chain made up of

A

Carbon and Hydrogen

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6
Q

What is a monomer

A

Small, unreacted single molecule for polymer

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7
Q

What is a mer

A

single repeat unit of a polymer

Polymer = entire polymer chain

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8
Q

What is polymerisation

A

When monomer molecules react together to form polymer chains

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9
Q

Degree of polymerisation formula??

A

n= (number of mer units) / (polymer molecule)

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10
Q

Increasing a polymer chain length creates?

A

A stronger material, increased stiffness, higher melting point

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11
Q

What is a linear chain polymer

A

a polymer consisting of a single continuous chain of repeat units

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12
Q

What is a branched chain polymer

A

a polymer that includes side chains of repeat units connecting onto the main chain of repeat units

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13
Q

What is a hyper branched chain polymer

A

a polymer consisting of a constitutional repeating unit including a branching groups

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14
Q

What is a cross linked polymer

A

a polymer that includes interconnections between chains

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15
Q

What is a net work polymer

A

a cross linked polymer that includes numerous interconnections between chains

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16
Q

What are the three classes/groups of polymers

A

Thermoplastics, Thermosets, Elastomers/Rubbers

17
Q

What is the chain structure of a thermoplastic like?

A

Long chains with very limited or no cross-linking which behave in a plastic ductile manner

18
Q

Examples of Thermoplastic materials

A

Nylon, polyethylene, polystyrene, PVC

19
Q

What does POLY MER stand for?

A

Many Units

20
Q

What is the chain structure of a thermoset?

A

Highly cross-linked, 3D network structures

21
Q

Thermoset mechanical properties?

A

Birttle, decompose when heated

22
Q

Examples of Thermoset materials

A

urethane, epoxy, polyester,

and silicone

23
Q

Elastomers and rubbers chain structure

A

Light cross-linking, allowing the material to return to its original shape without plastic deformation

24
Q

What is a homopolymer

A

A polymer consisting of only one type of constitutional repeating unit

25
Q

What is a copolymer

A

A polymer consisting of two or more constitutional repeating units (A-B )

26
Q

What is a Polymer Crystal

A

Ordered atomic arrangements involving molecular chains

Polymers can be crystalline

27
Q

Can a polymer be completely Crystalline?

A

No

28
Q

Max percentage of polymer degree of crystallinity?

A

95% (HDPE)

29
Q

What two compositions make up a polymer structure diagram?

A

Amorphous regions & Crystalline regions

30
Q

affects of increasing the crystallinity of a polymer

A

increase the strength and rigidity of the polymer

31
Q

2+2=4, -1 =3

A

Quick Maths

32
Q

How can plastics be formed?

A
Injection moulding (thermoplastics and some thermoset)
Extrusion
Blow Moulding
Extrusion Blow Moulding
Injection Blow Moulding
Compression and transfer moulding