Polymer Revolution Flashcards
Allene with 2 c=c bonds
Diene eg hexa-1,3-diene
Bond angle around C=C is always
120
Electrophile definition
Either positive ions or molecules with a partial positive charge on one of the atoms. When they react they accept a pair of electrons.
Alkenes undergo what form of addition
Electrophiilic
Test for Alkenes
Bromine –> red-brown to colorless
Br2(l) and alkene
Room temp and pressure alkene+2Br
Br2(aq) & alkene
Room temp and pressure and alcohol
Br attach and oh attach leaving HBr
HBr (aq) and alkene
Aq solution room temp and pressure H &Br join =alkane
H2O and alkene
Alcohol phosphoric acid/silica at 300 degrees/60atm or with conc. H2SO4 then H2O at 1 arm
H2 and alkene
Alkane apt catalyst, room temp and pressure or nickel catalyst at 150 degrees/ 5 atm
Chain lengths affect on polymer
Tensile strength- measure of how much force needs to be applied before a polymer snaps.
Increase Cl increases tensile as longer chains- more entangled
Longer chains have stronger intermolecular bonds between them so stranger to pull apart