POLYMER Flashcards

1
Q

Polymers

A

High molecular weight compounds formed by the repeated union of simple molecules called monomers.

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2
Q

Origin of the word Polymer

A

Derived from Greek words “poly” (many) - “mer” (unit or part).

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3
Q

Definition of Polymer

A

A macromolecule made up of repeating structural units linked by covalent bonds.

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4
Q

Process of Polymerization

A

The formation of polymers from monomers through chemical reactions.

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5
Q

Natural Polymers

A

Found in plants and animals - e.g. rubber - silk - cellulose - and proteins.

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6
Q

Synthetic Polymers

A

Man-made polymers created through chemical reactions - usually derived from fossil fuels.

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7
Q

Semi-Synthetic Polymers

A

Chemically modified natural polymers - e.g. cellulose acetate - vulcanized rubber.

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8
Q

Elastomers

A

Rubber-like polymers with weak intermolecular forces - e.g. Natural Rubber (polyisoprene) - Styrene-Butadiene Rubber (SBR) - Nitrile Rubber (NBR).

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9
Q

Fibers

A

Strong - thread-like polymers used in textiles and construction - e.g. Nylon - Polyester.

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10
Q

Liquid Resins

A

Low-viscosity polymers used in coatings and adhesives.

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11
Q

Plastics

A

Synthetic polymers that can be molded into different shapes.

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12
Q

Thermoplastics

A

Soften when heated and harden when cooled; process is reversible.

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13
Q

Thermosetting Plastics

A

Undergo irreversible chemical changes when heated - forming a rigid structure.

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14
Q

Definition of Thermoplastics

A

Polymers that soften when heated and harden when cooled (fully reversible process).

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15
Q

Intermolecular Forces in Thermoplastics

A

Moderate forces like van der Waals interactions and some hydrogen bonding.

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16
Q

Advantages of Thermoplastics

A

Versatile - durable - impact-resistant - recyclable - easy to reshape - chemically resistant - good electrical insulation.

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17
Q

Common Thermoplastics

A

Polyethylene (PE) - Polypropylene (PP) - Polyvinyl Chloride (PVC) - Polystyrene (PS) - Polytetrafluoroethylene (PTFE).

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18
Q

Resin Identification Code

A

A number system developed by the Society of the Plastics Industry (SPI) to classify plastic types.

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19
Q

Polyethylene Terephthalate (PET or PETE)

A

Formed by polymerizing ethylene glycol and terephthalic acid.

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20
Q

Uses of PET

A

Used in packaging - textiles - and plastic bottles.

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21
Q

Properties of PET

A

Strong - stiff - lightweight - resistant to chemicals and moisture.

22
Q

High-Density Polyethylene (HDPE)

A

A petroleum-based thermoplastic that resists chemicals and has high durability.

23
Q

Uses of HDPE

A

Plastic bottles - pipes - containers - and outdoor furniture.

24
Q

Polyvinyl Chloride (PVC)

A

One of the most widely used synthetic polymers.

25
Uses of PVC
Pipes - flooring - medical tubing - window frames.
26
Properties of PVC
Durable - resistant to chemicals - flame-retardant.
27
Low-Density Polyethylene (LDPE)
A flexible and corrosion-resistant polymer.
28
Uses of LDPE
Plastic bags - squeeze bottles - food packaging.
29
Limitations of LDPE
Not suited for applications requiring structural strength or heat resistance.
30
Polypropylene (PP)
A polyolefin slightly harder than polyethylene.
31
Uses of PP
Food containers - car parts - textiles - ropes - medical applications.
32
Properties of PP
Heat-resistant - flexible - chemical-resistant - lightweight.
33
Polystyrene (PS)
A widely used plastic known for affordability and insulation properties.
34
Uses of PS
Disposable cups - insulation - food containers - electrical insulation.
35
Definition of Thermosets
Polymers that undergo irreversible chemical changes when heated or cured with catalysts.
36
Cross-Linking in Thermosets
Prevents molecular movement after curing - making them heat-resistant.
37
Examples of Thermosets
Phenolics (PF) - Amino Plastics (UF and MF) - Polyester Thermosets (TS) - Epoxies (EP) - Polyimides (PI).
38
Phenolics (PF)
Machinable thermoset plastics with strong physical and chemical properties.
39
Uses of Phenolics
Electrical insulation - automotive parts - construction materials.
40
Properties of Phenolics
Thermally stable - electrically insulating - chemical-resistant.
41
Amino Plastics (UF and MF)
Made from aldehydes and amino compounds.
42
Uses of Urea-Formaldehyde (UF)
Adhesives - coatings - plywood laminates.
43
Uses of Melamine-Formaldehyde (MF)
Heat-resistant materials like countertops - tableware - and electrical components.
44
Polyester Thermosets (TS)
Low-cost materials with high strength-to-weight ratio.
45
Uses of Polyester Thermosets
Automotive parts - HVAC components - electrical applications.
46
Polyimides (PI)
High-performance plastics resistant to heat and chemicals.
47
Uses of Polyimides
Electronics - medical tubing - adhesives - gears - valve seats.
48
Properties of Polyimides
Low creep - high tensile strength - flame-resistant.
49
Epoxies (EP)
A widely used thermoset resin with strong adhesion and mechanical properties.
50
Uses of Epoxies
Coatings - adhesives - composites - electrical applications.
51
Properties of Epoxies
Resistant to moisture - heat - and chemicals.