Polar Covalent Bonds Flashcards
In between Bonds
In between bonds occur when atoms have significantly different electronegativity, but not great enough for the less electronegative atom to transfer its valence electrons to the other.
The difference…
Is great enough for the bonding electron pair to spend more time near the more electronegative atom than the less electronegative atom.
Intramolecular Forces
The forces between the atoms found inside a single molecule. (Ex. metallic, ionic, covalent bonds)
What can intramolecular forces determine?
They can determine the boiling points of substances (therefore the state). The stronger the intramolecular forces, the higher the boiling point.
Name the 4 types of intramolecular forces.
London dispersion forces
Dipole-dipole forces
Ion-dipole forces
Hydrogen bonding
London Dispersion forces
The simultaneous attraction between a temporary dipole in a molecule and the temporary dipoles in the surrounding molecules.
Dipole-dipole forces
This occurs in polar molecules due to simultaneous attraction between dipoles of the molecules
Dipole
A dipole represents the positive and negative regions in a molecule.
Ion-dipole forces
The force between a ion and a dipole molecule. Cations would be attracted to the negative side of a polar molecule and anions would be attracted to the positive side.
Hydrogen bonding
Hydrogen can form special types of intramolecular interactions when bonded to a highly electronegative atom in the second row only (N, O, F). The hydrogen is left with virtually no electron density and it becomes very positive.