Physical Chemistry- Acids, Bases and Kw Flashcards
Define an acid
A proton donor
Define a base
A proton acceptor
Define a strong acid
An acid that completely dissociates in solution to release H+ ions
Define a strong base
A base that completely dissociates in solution to release OH- ions
Define pH
-log[H+]
[H+] formula
10-pH
What is the acid dissociation constant for weak acids?
Ka=[H+][A-]/[HA]
What are the units of Ka?
moldm-3
What is Ka a measure of?
A quantitative measure of how strong a weak acid is
pKa formula
-logKa
How to calculate pH of a weak acid?
Ka=[H+]2/[HA]
Find [H+]
Use -log[H+]
Define Kw
Kw= [H+][OH-]
What is the effect of temperature on Kw?
Dissociation of water is endothermic
So equilibrium will shift to the to the right
So Kw will increase and therefore [H+] will increase so pH will decrease