Permanent dipole - dipole forces and Induced Dipole-Dipole Forces Flashcards
What kind of dipoles do polar molecules have
permanent dipoles
The molecule will always have a negatively and positively charged end
Forces between two molecules that have permanent dipoles are called?
The δ+ end of the dipole in one molecule and the…………….. in a neighbouring molecule are attracted towards each other
permanent dipole - dipole forces
δ- end of the dipole
Induced dipole - dipole forces exist between
all atoms or molecules
Induced dipole-dipole forces are also called
van der Waals forces or London dispersion forces
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The electron charge cloud in non-polar molecules or atoms are?
constantly moving
During this movement, the electron charge cloud can be more on one side of the atom or molecule than the other
During this movement, the electron charge cloud can be more on one side of the atom or molecule than the other this causes a ……… to arise
This causes a temporary dipole to arise
When a temporary dipole arises the δ+ end of the dipole in one molecule and the δ- end of the dipole in a neighbouring molecule are attracted towards each other
Because the electron clouds are moving constantly, the dipoles are only …….
temporary
For small molecules with the same number of electrons what forces are stronger permanent or induced ?
Pd-pd forces are stronger than id-id forces in smaller molecules with an equal number of electrons
Butane and propanone have the same number of electrons
Butane is a nonpolar molecule and will have induced dipole forces
Propanone is a polar molecule and will have permanent dipole forces
Therefore, more energy is required to break the intermolecular forces between propanone molecules than between butane molecules
So, propanone has a higher boiling point than butane
Exam Tip
Remember: Intramolecular forces are forces within a molecule, whereas intermolecular forces are forces between a molecule.