Periodicity Flashcards

1
Q

Meaning of periodicity

A

The occurrence of patterns in the periodic table

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2
Q

periodicity across a row

A

The atomic number increases for each successive element and the number of energy levels is the same

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3
Q

periodicity down a group

A

An occupied electron energy level is gained

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4
Q

down a group atomic size/covalent radius

A

Increases

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5
Q

across a row atomic size/covalent radius

A

Decreases

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6
Q

What is covalent radius

A

half of the distance between the nuclei of two bonded atoms of an element

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7
Q

Why is there is no covalent radius data for the noble gases

A

because they are monatomic elements

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8
Q

Why does covalent radius increase when going down a group

A

elements within the same group have one more occupied energy level as you go down the group

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9
Q

Why does covalent radius decrease when going across a period

A

Atoms within the same period have an increased proton in the nucleus going down each element. The increased positive charge on the nucleus increases the attraction for the electron in the outer energy level and they are pulled closer to the nucleus, making atoms smaller

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10
Q

First ionisation energy

A

the energy required to remove one electron from each atom of one mole of gaseous atoms

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11
Q

Second ionisation energy

A

the energy required to remove one electron from each singly positive ion of one mole of the gaseous ions

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12
Q

What state symbol is essential in ionisation

A

g

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13
Q

Is ionistion endothermic or exothermic

A

Endothermic

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14
Q

Ionisation down a group

A

decrease

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15
Q

Ionisation across a period

A

increase

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16
Q

Cause of Ionisation down a group

A

One more occupied energy level

17
Q

Cause Ionisation across a period

A

Increased number of protons

18
Q

Explained Cause of Ionisation down a group

A

The electron removed is further from the nucleus so the electron is more shielded. The weaker electrostatic attraction makes it easier to remove the electron.

19
Q

Explained Cause Ionisation across a period

A

The increased positive charge increases attraction so it requires more energy to remove the electrons.

20
Q

Why are Second and third ionisation energies larger than the first

A

the extra positive nuclear charge(s) has greater electrostatic attraction for the outer electrons and therefore more energy is required to remove the electrons.

21
Q

What is Electronegativity

A

Electronegativity is a measure of the attraction an atom involved in a bond has for the electrons of the bond.

22
Q

What does higher electronegativity mean

A

The higher electronegativity, the more strongly the nucleus attracts electrons towards it.

23
Q

electronegativity down a group cause

A

One more occupied energy level

24
Q

electronegativity across a period cause

A

Increased positive charge on the nucleus

25
Q

Electronegativity down a group

A

decrease

26
Q

Electronegativity across a period

A

increase

27
Q

Electronegativity down a group explained

A

The electron removed is further from the nucleus so the electron is more shielded. This means there is weaker electrostatic attraction

28
Q

Electronegativity across a period explained

A

The nucleus has a stronger electrostatic attraction for the electrons.

29
Q

Why breaking full shells takes more energy

A

-Electrons are closer to the nucleus
-Electrons are less screened from the nucleus as there are fewer inner electron energy levels
Therefore there is more electrostatic attraction