periodic table and energy Flashcards
halide ions test
dissolve in nitric acid- prevent false pos from carbonate ions ppt out w Ag+
silver nitrate drowse
AgX ppt
cl white
br cream
I yellow
ammonia follow up test
cl dissolves in dilute
br in conc
I doesn’t
carbonates test
aqueous hcl
gas produced tested in limewater Ca(OH)2
effervescence cos co2 produced
sulfates test
acidify w dilute hcl
few drops of aqueous barium chloride
white ppt of BaSO4
ammonium ions test
aqueous sodium hydroxide
ammonia gas produced
very soluble in water so no effervescence
pungent smell/ red litmus paper blue
ionisation energy definition
energy required to remove one mole of electrons from one mole of atoms of an element in a gaseous state to form one mole of gaseous ions
factors that affect ionisation energy
atomic radius
nuclear charge
electron shielding
change in ionisation energy across a period
increases
nuclear charge increases so more nuclear attraction
no significant change in atomic radius
shielding same
change in ionisation energy down a group
decreases
nuclear charge increases
atomic radius increases
shielding increases
nuclear attraction decreases
why is there a rapid decrease in ionisation energy between the last element in one period and the first in the next
increased atomic radius
increased shielding
these 2 factors outweigh increased atomic charge
Cl2 colour in aqueous solution
pale green
Br2 colour in aqueous solution
yellow
I2 colour in aqueous solution
brown
Cl2 colour in organic solution
colourless
Br2 colour in organic solution
yellow
I2 colour in organic solution
purple
list the halogens in order of decreasing reactivity
Cl
Br
I
what colour are halide salts
colourless
why is organic solvent added after a displacement reaction between aqueous halide salt and aqueous halogen solution
to confirm a displacement reaction has taken place
what type of reaction occurs between
aqueous halide salt
and
aqueous halogen solution
displacement
group 2 reactivity trend down group
increases
does Be react w water
no
group 2 metal + water
group 2 hydroxide
how does Mg react w water?
slowly w cold
vigorously w steam to produce MgO instead of Mg(OH)2
group 2 metal + oxygen
group 2 oxide
what are group 2 oxides
white solids
group 2 oxide + water
group 2 hydroxide
which dissociates to form OH-
how does MgO react w water?
very slowly
hydroxide barely dissolves
pH trend of group 2 oxides down group
increases
more alkaline
because hydroxides become more soluble
use of Ca(OH)2
neutralise acidic soils
use of Mg(OH)2
neutralise excess stomach acid
colour and state of fluorine
pale yellow
gas
colour and state of chlorine
pale green
gas
colour and state of bromine
brown- orange
liquid
colour and state of iodine
grey
solid
trend in electronegativity of halogens
decreases down group
atoms get larger
nuclear attraction decreases
shielding increases
Cl2 + 2NaOH
NaClO + NaCl + H2O
NaClO is bleach/ sodium chlorate (1)