Percentage yield and atom economy Flashcards
Percentage yield
Atoms never lost or gained in a chemical reactions
Not always possible to obtain calculated amount of product
Reversible reaction
May not go to completion
Some product could be lost when separated from the reaction mixture
What is amount of product called
Yield
Percentage yield formula
(Yield from reaction/
maximum theoretical yield)x100
Atom economy
Measure of amount of reactant that end up in a useful product
Scientists choose reaction pathways with higher atom economy
Atom economy formula
(Relative formula mass of desired product/sum of relative formula mass of all products and reactants)x100
Production of ethanol
Hydration and fermentation
Hydration
Ethene reacted with steam to form ethanol
C2H4+H2O—->C2H5OH
Fermentation
Fermentation of glucose
C6H12O6——->2C2H5OH+2CO2
Choosing reaction pathways
Atom economy
Cost of reactants
Percentage yield
Rate of reaction
Equilibrium position
Usefulness of by products