PCOG- Part 2 Flashcards

1
Q

Classification of tannins based on

A

Goldbeater’s skin test

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2
Q

Classification of tannins based on Goldbeater’s skin test

A

Positive tannin which is true tannin (tanning test) there are two, hydrolyzavle and nonhydrolyzable or condensed tannin

Negative tannin (tanning test) which is pseudotannin

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3
Q

Tannins can precipitate

A

Proteins
Alkaloid
Glycoside

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4
Q

Soak a __ in __ ; rinse with __ and
_ in the _ to be _. _
with distilled water and transfer to a _. A _denotes the presence of tannins.

A

Soak a small piece of goldbeater’s skin in 2%
hydrochloric acid; rinse with distilled water and
place in the solution to be tested for 5 min. Wash
with distilled water and transfer to a 1% solution of
ferrous sulphate. A brown or black colour on the
skin denotes the presence of tannins.

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5
Q

Differentiate Hydrolyzable and non- Hydrolyzable/ condensed tannins

A

Pyrogallol Catechol

Bluish black with FeCl3 Greenish black with FeCl3

No precipitate in bromine water because it is completely solluble
+Precipitate in bromine water

Leather type: Bloom Leather ( common leather type)
type: +Tanner’s red

Readily hydrolyzed to yield
phenolic acids and sugars
+When they are treated with hydrolytic
agents, they tend to polymerize
yielding PHLOBAPHENES

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6
Q

It is the red insoluble compounds

A

Phlobaphens

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7
Q

What is the difference between hydrolyzavle tannins and condensed tannins based on OH number

A

3 OH ni Hydrolyzable

2 OH ni Condensed tannin

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8
Q

General test for condensed tannin

A

Matchstick test

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9
Q

MATCH STICK TEST:
When a match stick is dipped in _
followed by _ & _ The wood of the
matchstick has lignin.
.

A

MATCH STICK TEST:
When a match stick is dipped in tannin extract
followed by HCl & warmed near a
flame it turns pink in colour. The wood of the
matchstick has lignin.
Upon hydrolysis of the tannins due to HCl,
phloroglucinol is formed which reacts with the
lignin of the wood to produce the pink colour.

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10
Q

Upon hydrolysis of the tannins due to _ ,
Then what is formed

A

Tannin
Phroglucinol

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11
Q

Upon hydrolysis of the tannins due to HCl,
phloroglucinol is formed which reacts with the
_ of the wood to produce the _

A

lignin
pink colour

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12
Q

They are compounds of lower molecular weight than
true tannins and they do not respond to the goldbeater’s
skin test

A

Pseudotannin

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13
Q

Examples of Pseudotannin

A

Gallic acid: Rhubarb
Catechins: Guarana, Cocoa
Chlorogenic acid: Mate, Coffee
Ipecacuanhic acid: ipecacuanha

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14
Q

Nasa GC CI pseudo

A

Pseudotannin
Gallic acid: Rhubarb
Catechins: Guarana, Cocoa
Chlorogenic acid: Mate, Coffee
Ipecacuanhic acid: ipecacuanha

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15
Q

Example of tannins

A

WITCH HAZEL / HAZEL NUT / SNAPPING NUT
Nutgall
Black catechu

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16
Q

Black catechu

A

Acacia hundra

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17
Q

Witch hazel/ hazel nut and snapping nut is from the

A

leaves of Hammamelis virginiana

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18
Q

Nutgall is from the

A

Quercus infectoria (plants) and Cynips tinctoria (insects)

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19
Q

Sources of Hydrolyzable

A

Quercus infectoria
Nutgall

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20
Q

What is the source of condensed tannin

A

Black catechu

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21
Q

consists of fixed oils, fats and waxes

A

Lipids

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22
Q

Lipids is also known as

A

Lipins or lipoids

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23
Q

Differentiate fixed oils, fats and waxes

A

FO- Long chain unsaturated FA + glycerol

FATS
Long chain saturated FA+ glycerol

WAXES
Long chain FAb+ HMW such as cetyl alcohol and stearyl alcohol

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24
Q

Liquid at room temperature

A

Fixed oils

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25
Q

Solid at room temperature

A

Fats
Waxes

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26
Q

two carboxylic acid groups

A

Dicarboxylic acids

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27
Q

Oh My Such Good Apple Pie Sweet As Suga

A

2 Oxalic
7 Pimelic
3 Malonic
8 Suberic
4 Succinic
9 Azelaic
5 Glutaric
10 Sebacic
6 Adipic

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28
Q

USP test for lipids

A

Acid value
Ester Value
Saponification value/ Koettsdofer Value
Iodine value

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29
Q

Mg of KOH needed to neutralize free FA in 1 gram

A

Acid value

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30
Q

Mg of KOH needed to saponify esters in 1 gram

A

Ester value

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31
Q

It is the amount of Acid value - Ester value

A

Koettsdorfer value or saponification value

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32
Q

Gram of iodine absorbed by 100g of sampel

A

Iodine value

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33
Q

Example of Non drying and it’s iodine value range

A

Lesser than 100
Olive, almond

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34
Q

Example of semi drying and it’s iodine value range

A

100-120
Cottonseed, sesame

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35
Q

Example of drying and it’s iodine value range

A

Greater than 120
Linseed
Cod liver oil

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36
Q

Biological sources of Oil

A

CPP
COP
RS
CS
ACL

Coconut oil
Palm oil
Palm kernel oil
Castor oil
Olive oil
Peanut oil
Rapeseed oil
Soya oil
Cottonseed oil
Sesame oil
Almond oil
Corn oil
Linseed oil

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37
Q

Coconut oil part
From
Family

A

seed kernels of the coconut palm,
Cocos nucifera Linne’

(Fam. Arecaceae)

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38
Q

Palm oil
part
From
Family

A

freshly part (mesocarp) of the fruit
Elaeis guineess
(Fam Arecaceae)

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39
Q

Obtained as a minor product during processing of
oil palm fruit.

A

PALM KERNEL OIL

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40
Q

It is obtained from palm kernels after separation,
drying and cracking of the shell of the nut.

A

Palm kernel oil

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41
Q

Palm kernel is obtained through from palm kernels after __of the nut.

A

separation,
drying and cracking of the shell

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42
Q

Castor oil
Parts
SN
Family

A

ripe seed of
Ricinus
communis Linne’
(Fam. Euphorbiaceae)

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43
Q

Uses of castor oil

A

stimulant cathartic at 15- 60 ml
emollient effect
plasticizer
in flexible collodion

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44
Q

is an ingredient in a vaginal jelly for
restoration and maintenance for vaginal acidity.

A

Ricinoleic acid is an ingredient in a vaginal jelly for
restoration and maintenance for vaginal acidity.

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45
Q

Olive oil part
Sn
Family

A

Fixed oil obtained from the ripe fruit of
Olea europea
Linne
Fam. Oleaceae)

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46
Q

It is sometimes called SWEET OIL

A

Olive oil

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47
Q

Preparation for olive oil

A

( cold pressed) Virgin oil

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48
Q

Extracted with less pressure

A

First Grade virgin olive oil

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49
Q

Pulp in #1 is extracted with
more pressure

A

Second grade virgin olive oil

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50
Q

Extracted with hot water

A

Techincal Oil

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51
Q

Extracted with S2

A

Sulfur Grade

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52
Q

Fallen and decomposing

A

Tournant Oil

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53
Q

Peanut oil
Part
Sn
Family

A

Ripe fruit or seed of
Arachis hypogaea Linne’
(Fam.
Fabaceae)

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54
Q

Peanut oil fruit is a true nut? T or F

A

False
The fruit is not a true nut because the immature pod
penetrates the soil and ripens underground

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55
Q

is the fixed oil obtained from the seeds of Brassica
campestris,

A

Rapeseed oil

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56
Q

Rapeseed oil
Part
SN

A

seeds
Brassica
campestris,

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57
Q

The oil consists of mixture of triacylglycerols that
are rich in unsaturated fatty acid

A

Rapeseed oil

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58
Q

It consist canla oil

A

Rapeseed oil

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59
Q

Soybean oil part
SN
Fam

A

ripe seed
Glycine soja
Fam. Fabaceae)

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60
Q

The seeds contain about 35% of carbohydrates, up to 50% of protein
substance, up to 20% of the fixed oil, and the enzyme, UREASE

A

Soybean oil

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61
Q

Soybean oil contains

A

35% of carbohydrates,
up to 50% of protein
substance,
up to 20% of the fixed oil,
UREASE

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62
Q

WULZEN ANTI-STIFFNESS FACTOR

A

STIGMASTEROL

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63
Q

Use of tannin, Industrially

A

Industrially: in leather tanning, ink manufacture

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64
Q

Use of tannin medically and in labs

A

Medicinally: astringent, hemostatic, antidiarrheal,
antidote in alkaloid and heavy metals toxicity.
In labs: reagent for detection of proteins, alkaloids
and heavy metals because of their precipitating
properties.

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65
Q

Cottonseed
Part
SN
family

A

seed of
Gossypium
hirsutum or of other species of Gossypium
(Fam.
Malvaceae).

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66
Q

Refined fixed oil, obtained from the
seed of
cultivated plants of various varieties of Gossypium
hirsutum or of other species of Gossypium (Fam.
Malvaceae).

A

Cottonseed oil

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67
Q

Halphen test

A

Cottonseed oil

68
Q

is the seed of
one or more cultivated varieties of Sesamum indicum
Linne’ (Family Pedaliaceae)

A

SESAMUM SEED OR SESAME SEED

69
Q

SESAMUM SEED OR SESAME SEED
Part
SN
Family

A

seed of
Sesamum indicum
Linne’
(Family Pedaliaceae)

70
Q

Baudouin test

A

Sesame oil

71
Q

Their taste is sweet and oily

A

Sesame oil

72
Q

Used as poppy seeds on breads and rolls

A

Sesame oil

73
Q

almond oil
Part
SN
Family

A

ripe
seeds
Prunus amygdalus
(Fam. Rosaceae)

74
Q

Sweet almond and bitter almond consist of the ripe
seeds of the different varieties of Prunus amygdalus
(Fam. Rosaceae)

A

Almond oil

75
Q
A
76
Q

Refined oil obtained from the embryo of the Zea
mays (Fam. Poaceae)

A

Corn oil

77
Q

Corn oil
Part
sn
Family

A

embryo
Zea
mays
(Fam. Poaceae)

78
Q

The oil-rich embryos (Often called )

A

The oil-rich embryos (Often called GERMS)

79
Q

GERMS) are
separated by a during the preparation
of

A

FLOTATION
CORN STARCH.

80
Q

Also called Flaxseed oil

A

Linseed oil

81
Q

A fixed oil obtained from the dried, ripe seed of Linum
usitatissimum Linne’ ( Fam. Linaceae)

A

Linseed oil

82
Q

Linseed oil
Part
Sn
Family

A

dried, ripe seed
Linum
usitatissimum Linne’
( Fam. Linaceae)

83
Q

Biological sources of fats

A
  1. Cod liver oil
  2. Fats and related coumpounds ( theobroma oil, lanolin ( hydrous wool fat), undecylenic acid
  3. Waxes ( spermaceti, jojoba oil, beeswax/ yellow wax, carnuba wax)
84
Q

From the fresh livers Gadus morrhua Linne’

A

Cod liver oil

85
Q

Cod liver oil Active constituent-

A

Myristic and palmitic acid

86
Q

Cod liver oil uses

A

Sources of Vit. A and D

87
Q

Sclerosing agent

A

Sodium morrhuate

88
Q

Indicated for varicose veins

A

Sodium morrhuate

89
Q

Also known as sweet oil

A

Olive oil

90
Q

Test for olive oil

A

Millions test

91
Q

Also knwon as arachis oil

A

Peanut oil

92
Q

Also kneon as benene oil

A

Sesame oil

93
Q

Goldbeater’s skin is a membrane prepared from the
__and behaves similarly to an__

A

intestine of the ox
untanned hide.

94
Q

Give example of phenolic acids

A

Gallic acid or gallo tannins
And ellagic acid or ellagic tannin

95
Q

Why does matchstick test hydrolyzed?

A

Because of HCl

96
Q

Lignin reacts with the phroglucinol to form

A

Pink color

97
Q

Agalalal ni rhubea

A

Gallic acid: Rhubarb

98
Q

Cat naguara ka cocoan ka man

A

Catechins: Guarana, Cocoa

99
Q

Ma’am chlor, mate co

A

Chlorogenic acid: Mate, Coffee

100
Q

Black chuna acacia

A

Black catechu - acacica chundra

101
Q

Fa + alcohol=

A

Lipids

102
Q

Examples of lipids

A

FIXED OILS
fats
Waxes

103
Q

Food for the gods

A

Theobroma oil

104
Q

Wool of ovis aries

A

Lanolin

105
Q

From castor oil

A

Undecylenic acid

106
Q

Undecylic acid is used as

A

Antifungal

107
Q

Example of undecylenic acid

A

Caldesene

108
Q

Caldesene is used for ( indicated for)

A

Diaper rash

109
Q

Example of waxes

A

Spermaceti
Jojoba oil
Beeswax/ yellow wax
Carnuba wax

110
Q

Waxes refers to
High molecular weight alcohol; in plants: ___

A

protection
from penetration and loss of water

111
Q

Physeter macrocephalus

A

Head of sperm whale

112
Q

cetyl ester wax

A

Synthetic spermaceti

113
Q

Seed of Simmondsia chinensis

A

Jojoba Oil

114
Q

Components of Spermaceti

A

Head of sperm whale
Synthetic spermaceti

115
Q

Honeycomb of bees

A

Beeswax or Yellow wax

116
Q

Stiffening agent in plasters and cerates

A

Beeswax or Yellow wax

117
Q

“white wax” bleached yellow wax

A

Beeswax or Yellow wax

118
Q

Leaves of Copernicia prunifera

A

Carnauba wax

119
Q

commonly used to designate basic heterocyclic
nitrogenous compounds of plant origin that are
physiologically active

A

Alkaloid

120
Q

Families rich in alkaloid

A

Rubiaceae
Apocynaceae
Papaveraceae
Solanaceae
RAPS

121
Q

FAMILIES FREE OF ALKALOID

A

Rosaceae (Rose Family)
* Lamiacea/Labiatae (Mint Family

122
Q

Most of the alkaloids are _ although
a few are amorphous.

A

crystalline solids,

123
Q

Alkaloids are crustalline solids however, what are the excemption?

A

CANS
Coniine
Arecoline
Nicotine
Sparteine

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