Paper 1: BCS, CP Flashcards
Describe denture base material
PMMA powder + MMA liquid
- PMMA = MMA pre-polymerised into powder via suspension polymerisation
- acts as filler as doesn’t polymerise more
Powder + Liquid HC using Dough Technique
Advantages of using HC Dough Technique
Using MMA alone: vol. shrinkage 21% (7% linear shrinkage)
- 2/3 replace w/ PMMA vol. shrinkage 7% (~2% linear)
Exotherm red.
Discuss composition of denture base PMMA
Powder
- PMMA spherical beads 10-200mmetre
- benzoyl peroxide (0.2-0.5%); initiator
- pigments (1-2%)
- Ti/Zn oxides; opacifiers
Liquid
- MMA
— volatile, flammable
— store dark glass bottle; avoid spontaneous polymerisation = extend shelf life
- ethylene glycol dimethacrylate (10%); cross-linking monomer
— form covalent bonds b/w PMMA chains
— improve craze resistance
— too much = brittle
- hydroquinone (0.0006%); inhibitor
— react w/ FRs that form in bottle
— form stabilised FRs; can’t initiate polymerisation
Activation requirements for HC polymerisation
Initiator (benzoyl peroxide) + heat (~80)
Discuss stages of HC polymerisation of PMMA
PMMA + MMA mixed -> Dough formed which is heated (80)
FR polymerisation occurs forms cured plastic polymer
Initiation: FR attack MMA double bond
Propagation: (chain growth); MMA monomers add to chain
Termination: 2 growing chains meet; FRs combine form stable covalent bond
Discuss the formation of crazes in denture bases
Internal strains due to thermal contraction
- minimise: use acrylic teeth, allow flask to cool slowly
Relieving produce tiny defects (crazes)
- form cracks which grow = #
Form in response to;
- heat; polishing
- differential thermal contraction around porcelain teeth
- attack by solvents; pt drinking alcohol
Discuss the formation of porosities in denture bases and why this is problematic
Exothermic: if over BPt (MMA 100.3)
Gaseous: incorrect curing; monomer vaporises leading voids
Contraction: flasks not kept under Constant Spring pressure during curing cycle
Granular: incorrect mixing/packing; structural deficiency due to loss of monomer
Problem
- H2O fills voids
- unreacted monomer (toxic) leach out
- further voids -> more H2O absorbed
- leads to crazes + failure
Advantages of HC PMMA denture base
Glass transition temp: 105/125 (high)
- well above temp. encountered in use
— polishing, cleaning
Specific gravity: low; doesn’t fall out
Aesthetic
Manufacture + repair easy
Good longevity: 5-10yr
Disadvantages of HC PMMA denture base
Toxicity: residual monomer (0.5%)
- contact dermatitis, mucosal irritation
Elastic modulus: 2.6GPa (low)
Impact strength: low (cracks grow), brittle
Fatigue strength: low; major cause failure
Abrasion resistance: low
Thermal conductivity/diffusivity: low; is insulator
- potentially scald as don’t feel temp.
Dimensional stability: polymerisation shrinkage
Discuss rubber reinforcement of HC acrylics
Butadiene styrene
- introduce rubber phase
- high impact acrylics
- cracks stop growing when rubber domains reached
- high degree of resistance to #
- lower flexural modulus; long term fatigue failure due to excessive flexure
Discuss potential fibre reinforcements of HC acrylics
Carbon: difficult handling, poor aesthetic
Polyaramid plain fabric (Kevlar)
- ineffective: poor bonding b/w resin and fibres
Ultra-high MWt polyethylene (UHMPE)
- neutral colour
- biocompatible
- low density
- surface treated for bonding to resin
- fabrication T consuming
Glass: most promise
- hydrophilic glass + hydrophobic PMMA problematic
- incorporated in resin as short fibres; in cloth or loose form
Explain why HC PMMA dentures need to be kept in H2O
In storage/mouth absorbs ~2% H2O
If drys out will absorb >2% H2O
If this continues crazes form
- due to relieving IS + residual monomer leaching
- crazes -> cracks -> fail; red. longevity
Uses for RT PMMA
Denture repair Relining denture bases Additions to denture Special trays Temp. crown and bridge
How is RT cured acrylic mixed?
RT PMMA (pre-polymerised MMA) powder + RT MMA monomer liquid mixed in Dough Technique
Composition of RT cured PMMA
Powder
- PMMA; finer particle size cf HC
- BP; initiator
- colour pigments
- Ti/Zn oxides; opacifiers
Liquid
- MMA monomer
- hydroquinone; inhibitor
- N,N-dimethyl-p-toluidine (DMPT); activator
Describe the RT polymerisation process of RT PMMA
Liquid + powder mixed
PMMA beads dissolve in MMA liquid
Activation: DMPT breakdowns BP liberating FRs
FRs attack MMA double bonds
- follows initiation, propagation + termination stages
~10min cure
How does the finer particle size of RT PMMA powder affect the curing process?
More rapid diffusion of MMA into PMMA beads
- rapidly gelates to hard mass
Advantages of RT PMMA cf HC PMMA
Cheaper
Less technician T; don’t have to send to lab
Chair side use
Disadvantages of RT PMMA cf HC PMMA
Physically weaker
- low MWt PMMA affect mechanical properties
- > residual monomer (3-5%) (not all able to polymerise)
— leaches -> porosities
Aesthetics: poor stability; DHPT causes yellowing
Tg: lower (70-80)
Porosity
- more rapid gelation
- hand mixing incorporate air
Inc. H2O uptake
- low MWt
- loss of residual monomer
- porosity
Discuss PEMA; what it is, monomers it can be mixed with, Tg
Higher methacrylate (cf PMMA) powder mixed w/ (usually) higher MWt monomers using Dough Technique
Monomers
- can’t use MMA = incoherently mixed product
- none = tissue conditioner
- higher MWt monomers (ethyl, butyl, hexyl)
Tg: 65 (
Uses of RT PEMA acrylics
Tissue conditioner (no monomer) Hard reliner Soft lining material Extension of special trays and dentures Temp. crown + bridge
Discuss PEMA tissue conditioners
PEMA mixed w/ no monomer
- no polymerisation occurs
- forms viscoelastic gel via polymer chain entanglement
- short life (3d); no polymerisation, alcohol volatile, plasticiser leaching
Uses
- denture lining; allow tissues to recover
- maxillofacial prosthesis; obturators
- functional impression materials
What is the function of PEMA powder in PEMA/EMA?
Same as PMMA
Acts as virtual filler
- dec. shrinkage
- lower exotherm
What is the purpose of soft lining materials?
Make denture more comfortable for pt in area has traumatised soft tissues
Function of plasticisers
Adjust viscosity of material
- make natural rigid material soft and rubbery
Lower Tg and elastic modulus
Dis/adv of soft lining PEMA
Adv - soft, rubbery acrylic - adheres well to acrylic denture base — contains acrylic group - Tg lowered by plasticiser
Disadvantages - hardens w/ T as plasticiser leaches — use as little as possible - short life due to hardening - biocompatibility; phthalate (banned in EU - use citrate)
Function of temp. crown
Mimic natural tooth
Protect prep. tooth while permanent crown being made
Made @ chair side
Composition of crown and bridge/extension PEMA
Powder
- PEMA
- BP
- colour pigments
- opacifiers
Liquid
- butyl methacrylate monomer
- hydroquinone
- DMPT
Adv of PEMA/BMA
Lower exotherm cf PMMA/MMA Less pulpal and soft tissue irritancy Non-volatile monomer Good handling Not brittle, ductile
Discuss light cure dimethacrylate materials
Uses
- composite filling
- temp. crown + bridge
Properties
- high modulus
- low exotherm
- adequate polymerisation shrinkage
Composition; 1 paste
- BisGMA/urethane dimethacrylate
- camphorquinone
- diluents
- fillers
- pigments
- DMPT
Discuss HEMA
Low viscosity liquid
Dry state: forms hard resin
Wet state: soft rubbery - hydrogel
- absorbs 10-100% H2O
Uses
- RMGIC, dentine bonding agent
- unsuccessful as soft lining
— absorbed too much liquid causing to swell
Discuss cyanoacrylates
Polymerise v quickly @ body temp
Used as surgical glue Dental uses - PD surgery - adhesive for dentine (bonds to collagen) - endodontic cement
Full strength within 24h
- higher moisture + thinner bond-line = faster cure
6 factors which keep dentures in place
- Saliva
- Muscles
- U and L teeth when biting
- Gravity (L denture)
- Denture clasps (direct)
- Denture rests (indirect)
Discuss how saliva can aid denture retention and the factors affecting this
Weak glue: b/w denture and tissues
- clinically unlikely to resist displacement
Suction: peripheral seal around denture
Factors
- dry mouth (poor)
- thin saliva layer (good)
- well-fitting denture (good); flange fills width of sulcus
Posterior ‘post. dam’ seal: artificial ridge created in denture to seal saliva
- border b/w hard and soft palate
Discuss how muscles and teeth can support dentures
Muscles
- learn to control denture using musculature; dependent on health
- post. tongue naturally rest on post. denture
Teeth biting together
- uneven/stable: dentures will slide
- correct occlusion (bite together in RCP); dentures stable
Define denture support, retention, stability
Support: ability to resist displacement towards tissue (O loading)
Retention: ability to resist displacement away from denture bearing area perp. to tissue surface at rest
Stability: ability to resist displacement in relation to underlying bone during function in any direction
Discuss what affects denture support and how to check support
Depends
- amount of coverage of underlying tissues/denture bearing area (more = better)
- condition (firmness) of underlying tissues/denature bearing area (firmer = better)
Check
- press O surface bilaterally; see if moves
- see how much area covered; denture extension ideal?
- signs of trauma?
Explain why an U complete denture has better support and is less likely to cause trauma
Larger fit surface and covers more underlying tissue and bone (more support)
Thus O forces distributed over larger surface area (less trauma)
Discuss factors affecting denture retention and how to check retention
Depends
- adhesion b/w denture, saliva, mucosa
- area covered
- adaptation to tissue
- border seal (suction)
- muscular control (tongue, cheek)
- gravity (L)
Check
- hold onto denture teeth, try to pull away from tissues
- press incisal edge U ant.; does back lift?
Discuss factors affecting denture stability and how to check stability
Depends
- degree of support and retention
- degree of alveolar bone reposition
- area covered
- freedom to make excursive movement
- consistency of supporting tissue
- position of teeth and design of polished surfaces
- correct vertical and horizontal O relationship
- level of O plane
Check
- history
- press O surface unilateral
- observe denture during function
Ideal properties of successful denture
Comfortable Strong enough Tolerable Adequate stability Atraumatic Aesthetic
Main components of RPD
Saddles
Rests
Clasps
Major + minor connectors
Discuss RPD saddles
Part that covers edentulous ridge
Usually (not always) incl. replacement teeth
Note: not all edentulous ridges restored by saddles
Function and types of RPD rests
Main support provider
Function
- transmit O forces to teeth along longitudinal axes
- maintain O relationship of denture base to abutment teeth
- prevent trauma to gingiva
- provide some lat. stability
- prevent food packing b/w abutment teeth and base
Types
- occlusal: pre/molars
- cingulum: canines
- incisal: outdated
- ring: wraps all way round tooth
What is a rest seat? Function
Any prepared surface on abutment teeth to take rest
Function
- provide O space b/w U+L teeth to allow adequate metal thickness
- provide more suitably inclined bearing surfaces cf natural teeth
- provide shape of surface desirable for amount of bracing
How to decide where to position RPD rests?
Adjacent to saddle
Adequate PD attachment of abutment teeth
Equally distributed; opposite
Adequate O space
Function, types, components and location of clasps
Provide retention
Function
- utilise resistance of metal to deformation
- engage extra-coronal undercuts
- usually natural undercuts
Types
- occlusally approaching
- gingivally approaching
- ring
Components
- rest
- retentive arm; engages undercut
- reciprocal arm; thicker, firm, doesn’t engage, resists displacement
- minor connector
Location
- adjacent to saddle
- spread around arch
- only need 2 diametrically opposed
Discuss Kennedy classification of dentures
Suggests/governs partial denture design
1: bilateral edentulous areas post. to remaining teeth; free end saddles
2: unilateral edentulous area post. to remaining teeth
3: unilateral edentulous area w/ teeth ant. + post.; bounded saddle
4: single, bilateral edentulous area ant. to remaining teeth; crosses midline
Discuss Applegate’s rules applied to Kennedy Classification
Missing 7+8 discounted if not being replaced
Most post. edentulous area determines classification
Modification spaces: additional edentulous areas (Class 2 mod 2)
Class 4: no modifications
Importance of denture support and how it can be gained
Importance
- red. movement on loading
- red. trauma
- improve distribution loading
Gaining: any part of denture that sits on bearing surface - hard tissue: teeth, hard palate — tolerate axial loading — feedback prevents overloading — as low as 20microm displacement - soft tissue: alveolar ridge, hard palate — loading can cause pain/trauma — limited feedback — displacement >500microm
Ways in which denture retention can be gained w/ natural teeth
Frictional contact
Clasps
Sectional denture
Precision attachments
Discuss frictional contact, sectional dentures and precision attachments
Frictional Contact
- most mucosa-borne acrylic dentures req. friction b/w base + natural teeth for retention
- guide planes enhance effect
— also improve clasps; restrict path of removal to 1 path
Sectional Dentures
- 2 parts w/ different paths of insertion
- when seated lock together by hinge or parallel split posts
- exploit undercuts on M and or D of abutment teeth
Precision Attachments
- depend on friction b/w machined M and F parts
- req. cast restorations on abutment teeth
- usually intra-coronal; may be extra-coronal
Define major connector (RPD)
Unit of denture that connects components on 1 side of arch to the opposite side
Part of denture to which all other components are attached
Principles of major connector design
Rigidity
Must not impinge moving tissue
Avoid pressure on gingiva
Adequate relief when indicated; bony prominences, tori
Supported by rests
Borders sited and contoured for tolerance
Types of mandibular major connector
Lingual Bar
Dental Bar
Lingual Plate
Buccal Bar
Discuss lingual bar and space req.
Conventional and sub-lingual types
Kennedy connector
Not sit on gingival margins
Space
- at least 3mm clear of gingival margins
- clear of moving tissues of FOM
- adequate dimensions for rigidity
- at least 7mm b/w gingival margin and FOM
Discuss dental Bar/connector
Sits across teeth Req. crown height of 8mm - 2mm clear of incisal edge; don’t see - 2mm clear of gingival margin - 4mm depth for rigidity (+ 2mm thickness)
Discuss lingual plate
Only used when necessary Covers all gingival margins + teeth - unfavourable - accumulation of plaque - difficult to clean Thin, wide Contoured for intimate contact w/ lingual surface
Maxillary major connectors
Palatal Bar
- ant., mid., post.
- usually ant. + post.
- narrow, thick (rigid) but bulky
- min. palate + gingival margin coverage
Palatal Strap
- thin, wide metal
- lots of palatal coverage, min. gingival coverage
Palatal Plate
- max. coverage; soft tissue hyperplasia, poor hygiene
- most comfortable, best support, rigid
Palatal Horseshoe
- covers gingival margin
- avoids palatal coverage; gag reflex
Discuss minor connectors
Connect major connectors to other components
Req.
- adequate O space
- emerge at 90 degree to gingival margin
- avoid sharp internal line angles
Discuss hygienic denture design and why it is important
Minimal amount of gingival margin coverage; free wherever possible
Why
- don’t cause plaque formation
- promote inc. in amount of plaque where gingival margin covered
- alter quality of plaque
Discuss how to minimise gingival damage in RPD design
Provide at least 3mm relief or none at all
If <3mm; gingival hypertrophy into small spaces making difficult to clean
Thus >3mm req. or none
Requirements of endodontic instruments
Flexible
Maintain cutting edge
Not corrode
Discuss SS endodontic material
Alloy of ace and <0.8% C; some Ni and Cr
Files prepared by twisting wire or machined (Hedstrom)
Flexibility depends on geometry, diameter, taper, twists
- rhombohedral (K-flex) most flexible
What is the only movement twisted SS endo instruments can be used in? Why?
Reciprocating up to 90 degrees
As
- clockwise: untwists file -> ductile failure
- anti-clockwise: tightens twist -> brittle failure
— usually fail anti-clockwise
Discuss the structure of endodontic Ni-Ti
Can exist in 2 crystal structures w/ different properties
Martensite
- low temp. form; body centred cubic
- low modulus (flexible), high strain @ break
Austenite
- high temp. form; monoclinic
- high modulus (rigid), low strain @ break
Discuss shape memory of Ni-Ti
Unique property
Deform NiTi with v low force @ lower temp
When heated through transformation temp recover original shape
- ortho use: apply pressure to teeth as recovers shape
Remove deformations by heating to 125 degrees
- endo: curve file for canal, removed by sterilising
Discuss superelasticity of NiTi
Can be strained much higher cf conventional alloys before permanent deformation occurs
Elastic deformation up to 8% cf SS 1%
Discuss causes of NiTi # and how it can be improved
Both ductile and brittle aspects Due to; - low yield stress - work hardening - structural imperfections produced during manufacture - fatigue
Improved by
- electropolishing machined surfaces
- ion implantation or surface coating to harden
Compare NiTi and SS properties
Strain: 8% vs 1% NiTi - higher strength, lower modulus - machines; continuous rotation - expensive - better fatigue life, flexibility
SS
- used for hand instruments
- cheaper, can be pre-curved
Both suffer fatigue
Discuss 3 main irrigants used in endo
NaOCl (0.5-5.25%) 1%
- dissolves proteolytic debris
- antibacterial
- affects instruments
- possible toxicity
Chlorhexidine 2%
- usually chlorhexidine deglutonate
- alternative to NaOCl
- antibacterial
- adheres to dentine
- not proteolytic
Ethylene Diamine Tetra-acetic Acid (EDTA) 10-18%
- lubricant
- dissolves smear layer; calcified canals
- use in conjunction w/ NaOCl
Discuss endodontic medicaments
Non-setting Ca(OH)2 (pulpdent)
- most common
- alkaline pH12
- antibacterial: OH- release -> damage bacteria preventing growth
Ledermix
- mix; cortisone derivative and broad spectrum AB
— 1% triamcinolone (anti-inflammatory)
— 3% demeclocycline (AB)
- good for pulpal or PD inflammation
- endo-Perio lesion: spread from pulp -> PD tissue
Phenolic compounds Quaternary ammonium compounds - not effective - used near toxic level 1% Iodine - 2% Potassium-Iodide - low toxicity, antibacterial - staining; rinse w/ NaOCl
Discuss phases of gutta percha
60% crystalline, hard, rigid
Alpha - high temp., cooled slowly - softer - thermoplastic techniques — heated and injected into canal
Beta
- high temp., cooled rapidly
- rigid
- GP points
Composition of GP points
GP 19-22%
ZnO 59-75% filler
Heavy metal salts 1-17% radio-pacifier
Wax/resin 1-4% plasticiser
Properties of GP
Biocompatible Insoluble Thermoplastic - softens 60-65 - melts 100 (can’t heat sterilise) Light degradable (brittle) Swells in solvents (acetone, chloroform)
Alternatives to GP
Resilon
- thermoplastic polyurethane
- bioactive glass + radiopaque filler
- similar handle cf GP
- similar filling techniques
- softened by heat, soluble in solvents
- req. EDTA Tx and self-etch Prime for good bond
Silver
- rigid, corrodes
- discolour
Acrylic or Ti: solve corrosion problem
Discuss composition of ZOE for canal sealing
Powder - ZnO (MgO) - fillers; SiO2, Al2O3 - dicalcium phosphate - Zn salt Liquid - eugenol - other oils; olive, cotton seed - acetic acid (accelerate) - H2O (essential) Additive - iodides: bactericidal - Ag, Ba, bismuth salta: radiopacity - resins: improve adhesion to canal
Properties of ZOE
Moisture accelerate set Eugenol: allergy, inflammatory reaction, inhibit polymerisation Soluble H2O Obtundant Thermal insulator Good seal
Composition of setting Ca(OH)2
Paste 1: Base
- salicylate Ester: butylene glycol disalicylate
- TiO2, CaSO4, BaSO4 (fillers)
Paste 2: Catalyst
- Ca(OH)2
- ZnO
- toluene sulphonamide, Zn stearate (plasticiser)
Properties of Ca(OH)2
Alkaline: bactericidal Long working T Biocompatible High solubility; water weakens Moisture accelerate set
Discuss resin based canal sealers
Epoxy amine - good handle - good seal Polyketone/Polyvinyl resin, reinforced ZOE - cytotoxic when set Urethane dimethacrylate/BisGMA
Properties
- insoluble
- polymerisation shrinkage
- long working T
- good flow
- radiopaque
Discuss GI as canal sealer
Glass powder + PAA
Bonds to tooth
Short working T
Sets hard, difficult to remove
Discuss polydimethysiloxane canal sealer
Addition cured silicone (impression material)
Good working T Smooth, homogenous mix Good flow Insoluble No bonding Not antibacterial
Discuss mineral trioxide aggregate
Complex reaction
- hydration of tricalcium silicate -> hydrated calcium silicate gel + Ca(OH)2
Sets hard, mixed w/ H2O Strong Alkaline: initial 10.2, set pH12.5 Long set: 3-4h Expensive, difficult to handle
Classification of dental alloys
High noble
- > 40% Au
- > 60% noble metal; Pt, Pd
Noble: >25% noble
Base metal (Co-Cr, Ni-Cr, Ti)
- <25% noble
Requirements of RPD alloy
Biocompatible Easy to cast - high density: easily force out air of mould, fill w/ alloy - low MPt = low shrinkage Low casting shrinkage Easy to join/solder Easy to finish/polish Easy to adjust High modulus (rigid) High yield stress Good fatigue strength Good wear resistance Good corrosion/tarnish resistance
Composition of Co-Cr alloys
Co (50-65%); strength, hardness
- interchange Ni (0-30%); inc. ductility, dec. hardness
Cr (25-30%); hardness (solution hardening), resist corrosion (passive oxide layer)
Mo (4-6%); red. grain size, hardness (solution hardening)
C (0.2-0.5%); hardness + strength
- forms carbides which precipitate on slow cooling
- excess carbides = brittle
Small amounts: Fe, W, Mn, SI
Dis/adv Co-Cr alloy
Adv
- cheap
- hard, abrasion resistant
- high modulus (use in thin section)
- high yield stress
- low density, lightweight
- Ni-free biocompatible
- good thermal response
Disadv
- poor handling
— high casting temp, high cast shrinkage (~2%)
- low ductility
- rapid work hardening (can’t be adjusted)
- Ni sensitivity
- difficult to finish/polish (due to hardness)
— req. electrolytic polishing of fit surfaces
Composition of Ni-Cr alloys
Ni (60-80%); hardness, strength
Cr (10-27%); hardness (solution hardening) corrosion resistance (passive oxide layer)
Mo (2-14%)
Be (0-2%); carcinogenic
+ Al, C, Co, Cu, Mn, Ti
- fluidity, castability
- limit carbide precipitation, too much = brittle
Composition of T4 gold alloys
Au 60-70%; lowest amount as ductile Ag 4-20% Cu 11-16% Pt 0-4% Pd 0-5% Zn 1-2%
General rules for properties of gold alloys from T1-4
As go from T1-4
- hardness (Vickers), elastic modulus (rigidity), tensile strength inc.
- ductility, elongation @ break dec.
Compare properties of T4 gold cast and hard
Vickers hardness: 130-160; 200-240VH
Tensile: 410-520; 690-830MPa
Modulus: 95; 103GPa
Elongation: 5-25; 1-6%
Dis/adv of T4 gold alloys
Advantages - biocompatible - easy to — cast; low MPt, shrinkage 1% — finish/polish — solder - corrosion resistant - can be heat hardened (order hardening)
Disadvantages
- high density; uncomfortable for pt
- low yield stress; weaker
- low modulus; thick sections
- expensive
Discuss forms of Ti/alloys
Commercially pure Ti
- 4 grades of 99% Ti + varying amounts N, C, H, Fe, O
- Inc. O, Fe: inc. strength, Dec. ductility
Alloys - alpha: low temp., hexagonal - beta: high temp., cubic centred body - Ti6Al4V alpha + beta — V toxin replaced by Nb: Ti6Al7Nb
Compare properties of Ti6Al4V and cpTi (G1 vs G4)
Hardness: 320; 126-263VHN Tensile: 930; 240-550MPa Yield: 860; 170-480MPa Modulus: 113; 102-104GPa Elongation: 10-15; 24-15%
Discuss materials used for denture clasps
Wrought
- pre-mode, bought clasps, soldered on to framework
- SS, Au
- better flexibility (esp. Au) and strength
- Au: easy to adjust + solder, possible corrosion @ join w/ base metal
Cast
- cast w/ framework
- Co-Cr, T4 Au
Base metal clasps have limited adjustment (work hardening)
Aesthetic clasps
- thermoplastic acetal resin (polyoxymethylene)
- used w/ acrylic or Co-Cr RPDs
What are cold cure soft acrylics? What is their use?
Temporary soft lining materials
Soft, viscoelastic material
Use: Tx irritated mucosa supporting denture
- allow recovery of inflamed tissue from ill-fitting denture
- absorb some energy prod. by masticatory forces
- shock absorber b/w O surface denture + underlying tissue
- promote healing
Discuss properties of temporary SLM/RT soft acrylic
Generally inf. HC soft acrylic (long-term SLM)
3-5% residual monomer: irritant + fungal infection
Higher H2O uptake; monomer leach, space filled w/ H2O cf HC
Poorer mechanical properties cf HC
Temporary: 1-2 wk
Discuss composition of RT soft acrylics (temporary SLM)
Powder - PEMA — or copolymer of butyl and ethyl methacrylate — or PMMA - residual BP - opacifiers - pigments
Liquid - EMA — or BMA — or MMA - ethylene glycol dimethacrylate; cross-linking agent - dibutyl phthalate (or citrate) — phthalate = carcinogen — no chemical bond = leaching - DMPT; 3ry amine activator - hydroquinone
Compare functions or short term SLM and TC
Similar function, differ;
Composition: polymerisable monomer; ethanol, no polymerisable monomer
Setting: FR addition polymerisation; gelation + chain entanglement
Lifespan: 1-2 wk; 3d
What are tissue conditioners? What are their uses?
Soft, viscoelastic materials
Uses
- Tx irritated mucosa supporting denture (temp. SLM)
- temp. (3d) denture liner; Tx denture stomatitis
- functional impression material; wear provisional denture 24h
- piezograph
— impression moulded by tongue, lips, cheeks over 5-10min
- maxillofacial prostheses
Compare composition of Viscogel and Coe-comfort (TCs)
Viscogel Powder - PEMA — or copolymer B/EMA Liquid - plasticiser — butyl phthalyl, butyl glycollate, dibutyl phthalate — acetyl tributyl citrate - ethanol 6-15% - no monomer = no polymerisation
Coe-Comfort
Powder
- Zn undecylenate
— Zn: red. irritation + swelling of fungal infection
— Fatty acid: prevent growth fungus
Liquid
- Benzyl Benzoate: plasticiser, preservative
- ethyl alcohol: solvent; accelerate gelation
Discuss setting of TCs
Set via gelation (chain entanglement), physical process
On mixing, polymer beads (chains) swell in alcohol
- allows penetration of plasticiser b/w polymer chains
- polymer chains move more easily
Gel formed by polymer chain entanglement
Discuss factors than can affect handling of TC
Inc. powder:liquid
- inc. viscosity of gel
- affect final compliance (softness)
- inc. rate
To inc. rate
- inc. temp
- dec. MWt + particle size of polymer powder
- inc. ethanol
Advantages and disadvantages of TC
Adv
- simple
- use chair-side
- bond PMMA
- compliant (soft)
- viscoelastic
Disadv
- harden in mouth: ethanol + plasticiser leach
— ethanol lost within 24h (may be irritant)
- possible toxicity of plasticiser
- porous: ingress of microorganisms
- difficult to remove from denture
Discuss general properties of temporary SLM and TCs in relation to interaction w/ fluids and denture cleansers
Fluids
- high H2O uptake; stain, microbial colonisation
- plasticisers can leach
— inc. in presence of long-chain fatty acids, alcohol
- inc. surface roughness esp. soft acrylics
- more affected cf silicones (long term SLM)
Cleanser
- all affect SLM and TCs
- hypochlorite bleaches
- alkaline peroxide roughens surface, bleaches
- brush w/ soap
What are long-term SLMs? What are their functions?
Group polymeric materials
Last in OC >wks/mnths/yrs
Intended inc. comfort + support prosthetic Tx
Can’t red. forces transmitted by denture bearing area
Function
- evenly distribute masticatory forces + absorb some energy
— relieve mucosa from high mechanical stress
- deforms elastically, energy release as returns to original form
4 types of long term SLMs
HC addition silicone
RT vulcanised cured condensation silicone
RT vulcanised cured addition silicone
HC soft acrylic
Uses of long-term SLM
Long-term (wks-yrs), resilient linings Pt can’t tolerate hard denture base Utilise undercuts for retention Retention of complete dentures to implants Obturators and other prostheses
Disadvantages of long term SLM
Expensive: HC sent to lab
Difficult to modify and polish
Dec. denture thickness, inc. rigidity/hardness
- 1mm thick hardness as support of underlying tissue comes through
More prone to #
Ideal properties of SLMs
Nontoxic, nonirritant Bond PMMA Not support growth of Candida Permanently resilient + compliant Low H2O uptake (similar to PMMA 2%) Not affected by denture cleansers Easy to clean, not easily stained Sufficient mechanical strength + abrasion resistance Wetted by saliva
Compare the viscoelasticity of silicone-based and soft acrylic SLM
Silicone based recovery rate is faster
Soft acrylics can permanently deform
Discuss the composition and setting of HC addition silicone SLMs
Composition: one paste
- vinyl terminated poly(dimethyl siloxane)
- gamma-methacryloxypropyltrimethoxy silane (MPTS); cross-linker
- BP: initiator
- PMMA: filler
- colouring agents
Setting
- HC 100degrees for ~2hr; can be microwaved
- addition, FR polymerisation
- BP oxidises CH3 on neighbour siloxane chains to form cross-links
- silane acts as cross-linker
- methacrylate group reacts w/ denture base to form bond
Composition of RT vulcanised condensation silicone
Similar to impression material Base - silicone polymer w/ terminal OH groups - inert filler Catalyst - tetraethoxy orthosilicate; cross-linker - dibutyl tin dilaurate; catalyst - inert filler
Composition of RT vulcanised addition silicone
Base - vinyl terminated poly(dimethylsiloxane) - H+ terminated poly(dimethylsiloxane) - inert filler Catalyst - vinyl terminated poly(dimethylsiloxane) - Pt-based catalyst: chloroplatinic acid - inert filler
Other components in silicone SLMs
Bonding agent/Primer (all silicones)
- polymer in solvent
- can contain silane
- can contain MMA; bond PMMA denture
Glaze/Polish (RT vulcanised)
- smooth and seal trimmed areas
- not used in contact w/ tissue
- unfilled AS, some w/ solvent
Compare general properties of SLM silicones
RT vulcanised AS: better mechanical and adhesion to PMMA cf CS
HC AS: best adhesion and lower H2O cf RT vulcanised
Advantages and disadvantages of SLM silicones
Adv
- resilient
- compliant
- not adversely affected by OC
Disadv
- poor adhesion to PMMA
- poor tear strength
- hydrophobic: not wetted by saliva
- support growth of Candida
- 1-paste HC req. refrigeration (short shelf-life)
Composition of HC soft acrylic SLMs
Long-term SLM Powder - PEMA — E/BMA copolymer - residual peroxide
Liquid
- higher methacrylate monomer: E/BMA
— contribute to softness
- cross-linker: ethylene glycol dimethacrylate
- plasticiser: butyl phthalyl, acetyl tributyl citrate
— red. Tg below mouth temp
Discuss setting of HC soft acrylic SLM
As w/ HC PMMA: FR addition polymerisation on heating
Dough technique
Initiation: FR attack double bond
Propagation: monomers add to chain, chain growth
Termination: 2 growing chains meet, FRs combine forming stable covalent bond
Advantages and disadvantages of HC soft acrylic SLM
Adv
- initial compliance is good: retains softness
- wetted by saliva (hydrophilic)
- bond PMMA
- good tear resistance
- polished if chilled
Disadv
- hardens (plasticiser leach); toxicity
- high H2O absorption; plasticiser leach
- less resilient cf silicones; don’t remain soft
- permanent deformation can occur
Discuss waxes and dental waxes
Organic crystalline compounds; natural or synthetic
Thermoplastic moulding material
- solid @ RT
- heated to liquid phase thus is mouldable
Pyrolysed; melt and/or decompose -> H2O vapour + CO2
Individual wax
- sharp, well-defined MPt
- little use
Dental
- blend 2/+ waxes
- material w/ softening temp range over which is mouldable material
Composition of dental waxes
Wax: synthetic and 2/+ natural Small amount additives - gums: gum Arabic, tragacanth - fats: esters of FAs w/ glycerol - fatty acids - oils - natural (dammar, rosin) and synthetic (shellac) resins - pigments
Aim of additives in dental waxes
To give set of given properties of specific range of temps
Contain range of MWt that affect melting and flow properties
Chemical components of natural and synthetic waxes impart characteristic physical properties
7 types of natural wax
Paraffin: petroleum
- straight chain HC
- melt: 40-70
Microcrystalline: heavier petroleum fractions
- branched HC
- melt: 60-90
Ceresin: petroleum or lignite refining
- melt: 61-78
- use: inc. melting range paraffin
Carnauba: Carnauba Palm
- melt: 84-91
- use: inc. melting range + harden paraffin
Candelilla: small shrub
- melt: 68-75
- use: harden paraffin
Beeswax
- melt: 63-70
- use: modify paraffin
Spermaceti: sperm whale
- use: coating on floss
Discuss synthetic waxes w/ examples
Production
- combination of chemicals in lab OR
- chemical action on natural wax
Usage inc.; higher degree of refinement
Polyethylene: 100-105 Polyoxyethylene glycol: 37-63 Halogenated HC Hydrogenated HC Wax esters: reacting FAs + alcohol
Define melting range and flow (waxes)
Melting range
- range of temps at which each component begins to soften and then flows
Flow: movement of wax molecules which slip over each other (at high temp wax has low viscosity and flows)
- mobile as approaches melting range
- control of flow/melting range important in manipulating wax
- clinic: melting range of bite registration wax only slightly > mouth temp
— too high would be uncomfortable for pt
- lab: much higher melting range
Discuss excess residue and dimensional change (waxes)
Excess residue: wax film remaining on object after removal
- may result in inaccuracies in item being produced
- important in lost wax technique
Dimensional change
- waxes have greater thermal expansion and contraction cf any other DM
- important in pattern wax: duplicate restoration carved in wax
- if heated > melting range/unevenly = expansion > acceptable standards = inaccuracies
- on standing dimensional change due to release of residual stress
— invest and cast within 30 min after carving wax
How are stresses formed in wax?
Heating
Carving
Bending
Manipulating
Discuss types and uses of inlay wax
Is pattern wax
T1: medium, direct technique
T2: soft, indirect technique
- restoration made in wax -> metal/ceramic
Use: patterns for inlays, onlays, crowns
Ideal properties of inlay wax
Direct: soft, plastic > mouth temp
Indirect: solidifies < mouth temp
Carved w/o flaking or distortion
Colour contrast from tooth/die
V low residue on vaporisation (<0.1% @ 500 degrees)
Low thermal expansion (but high cf DMs)
No distortion @ moulding temp (no stress build up)
Softens w/ dry heat
Composition of inlay wax
Paraffin (60%): weak, flakes thus need additives
Carnauba (25%): inc. melting range/glossy finish
Ceresin (10%): modify toughness and carving
Beeswax (4%): red. flow @ mouth temp, red. brittleness @ RT
Dammar resin (1%): improve smoothness, crack and flake resistance, glossy finish
Discuss casting wax
Type of pattern wax
Use: patterns for partial denture framework
Composition: unknown, similar to inlay wax
Highly ductile: bend double @ 23 degrees w/o cracking
Class 1: easily adaptable 40-45
Class 2: adapts well to surface, not brittle on cooling
Class 3: burnt out w/o leaving residue
Discuss modelling wax
Use: set up artificial teeth for C denture
Composition
- paraffin or ceresin (70-80%)
- beeswax (12%)
- resins: natural or synthetic (3%)
- carnauba (2.5%)
- microcrystalline or synthetic waxes (2.5%)
Properties
- easily mouldable w/o cracking, flaking, tearing
- easy to carve
- melt and solidify repeatedly w/o changing properties
- no residue after removal w/ boiling water and detergent
Discuss boxing-in wax
Type of processing wax
- box wax as sheets
- heading as ribbon
Use
- build up vertical walls around impression before pouring
- beading: adapt around impression borders
Properties
- pliable @ RT
- retain shame @ 35 degrees
- slightly tacky
Discuss sticky wax
Type of processing wax
- adhesive wax
Use: temp joining of articles
- align # parts of acrylic denture
- align fixed partial denture parts before soldering
Composition
- rosin
- beeswax
- dammar
Properties
- RT: hard, brittle
- melted: sticky, adheres closely to applied surface
- # s on movement rather than distorting
Discuss impression wax
Use: O registry (edentulous impression) Composition - HC waxes: paraffin, ceresin, beeswax - Al or Cu: improve integrity and shape Properties - distorts when removed from undercut areas: only edentulous areas - soft/flows @ mouth temp; rigid @ RT
Discuss 4 other dental waxes
Wax rim/Bite rim: pattern wax
- use: restore O relationship, arrangement of teeth
- softening temp > mouth temp
- tough, resists #
Utility/Rope wax: adapt border of impression
Shellac denture base
- stable @ mouth temp
- high softening point
Base plate wax: pattern wax
- use: preparing wax patterns for prosthesis
- red or pink sheets
Compare mucocompressive and mucostatic impression materials
Mucocompressive/displacive
- viscous, record mucosa under load
- appliance has wider distribution of load during function (stable)
— compensates for differing compressibility of bearing area
— red. risk # due to flexion
- retention compromised as soft tissues return to original position @ rest
- examples: impression compound, high viscosity alginate/elastomer (polyether)
Mucostatic
- fluid, displace less
- record un-displaced tissue
- better retention as closer adaptation to tissue @ rest
- instability during function as tissues distort
- examples: impression plaster, ZOE, low viscosity alginate, light body addition silicone
Discuss non-elastic impression materials
Rigid materials; little/no elasticity
Any significant deformation = permanent deformation
Use: no undercuts, edentulous pt
Composition, properties and handling of impression plaster
Composition
- CaSO4 B-hemihydrate
- K2SO4; accelerator, anti-expansion
- borax; retarder (counteract K2SO4)
- colouring agents; contrast model plaster
Properties
- mix w/ H2O hemihydrate -> dihydrate
- expands on set; sets hard
- thinner mix cf model plaster
- flows into fine details e.g. ridges
- mucostatic
- no trays req.
- edentulous cases only
Handling
- mix; load tray, position, hold till sets
- may # on removal; retrieve and glue together
- beading wax adapted to periphery; indicate where impression ends
Discuss impression compound; composition, properties, handling
Composition
- resins
- waxes
- talc; filler
- stearic acid; lubricant
Properties
- thermoplastic
- poor thermal conductivity/flow
- not reproduce undercuts
- mucocompressive
- high viscosity; record full depth of sulcus if req.
Handling
- soften by heating in H2O @ ~60 degree
- load stock tray, position
Discuss ZOE impression paste; composition, properties, handling
Composition - paste 1 — ZnO — Zn acetate - paste 2 — eugenol — inert filler; kaolin, talc
Properties
- brittle when sets; #s
- accurate in thin sections
- initial low viscosity and pseudoplasticity
- mucostatic
Handling
- Zn eugenolate formed on mixing
- use v close fitting tray or existing denture
Use diminishing due to elastomers
- edentulous or relining
Uses of hydrocolloid impression materials
C/P dentures Ortho: base plate Mouth protectors Study models, working casts Duplicating models
Dis/advantages of alginates
Adv - setting behaviour — Na3PO4 (retarder) = viscous paste while seating — rapid once begins = min. impression T - cheap, reliable
Disadv
- H2O loss
— continual shrinkage post-set (cast immediately) = poor dimensional stability
— cover w/ damp gauze in plastic bag (few hrs)
- H2O/disinfectant immersion
— imbibition; initially swells
— shrinks; H2O soluble salts eluted
— prolonged immersion impractical and unsolved
- poor tear strength; large undercuts can’t be reproduced
- highly viscoelastic
— snap removal technique
— permanent deformation up to 1.5%; diminished if undercuts not deep
Dis/advantages of agar
Adv
- easy to use
- cheap
- good surface detail
Disadv
- syneresis (cast immediately) = poor dimensional stability
- imbibition; distortion
- poor tear strength; better cf alginate
- compatibility w/ model materials
- highly viscoelastic; permanent deformation up to 1%
Uses of elastomers
Accurate replica teeth + supporting tissues
- C/P denture, crown, bridge, inlay
Border moulding of special trays (polyether)
Duplicating of refectory casts
Bite reg
Dis/advantages of poly(dimethyl siloxane) impression material
Condensation silicone
Adv
- strength, dimensional stability cf alginate
- more elastic cf polyether/sulphide
- tear strength, elongation @ break adequate; undercuts reproduced
Disadv
- dimensional stability; 0.3-0.5% shrinkage 24h
- hydrophobic; detergents incorporated (may expand)
- mouth dry as possible
- mainly lab use
- erratic setting: liquid catalyst
- limited shelf-life: liquid catalyst
Dis/advantages of poly(vinyl dimethylsiloxane)
Addition silicone impression material
Adv
- best dimensional stability; <0.05% 24h
- elastic recovery v good cf polysulphide/ether
Disadv
- free H2O (plaster) react w/ unreacted Si-H -> H2 = porous model
— wait 20-30mins before casting
- tear strength, elongation @ break adequate; less cf CS
- hydrophobic
- natural rubber retard set; S poison Pt catalyst
- poor shelf-life, long set
Dis/advantages of polyether
Adv
- dimensional stability in air
- quick set cf polysulphide
- reliable
- clean handle
Disadv
- high modulus + low elongation @ break = tears easily (original impregum)
- dimensional stability in H2O/vapour; disinfection problematic
- permanent deformation
Dis/advantages of polysulphide
Adv
- strongest impression material: elongation @ break ~500%
Disadv
- dimensional stability: 0.1-0.2% shrinkage
- slow set
- dirty handling, unpleasant odour
- elastic recovery poor cf silicones, polyether
What are investment materials?
Ceramic material used to form moulds for dental castings
Used to compensate for shrinkage of alloy due to change from liquid to solid and thermal contraction
General requirements of investment materials
Withstand high temp and pressure Easy to manipulate, fast set Smooth surface to give smooth finish to casting and preserve fine detail Chemically stale @ temps used Porous enough to allow air/gas to escape Easily break away from casting Not react w/ alloy Sufficient strength to withstand casting Expand to compensate for shrinkage Inexpensive
3 general components of investment materials
Refractory: withstand temp, shrinkage compensation
- crystalline SiO2: quartz, cristobalite, tridymite
Bind: hold refractory particles together
Other additions: modify physical properties
Mechanisms of expansion of investment materials
Setting expansion of binding
- greater in presence of refractory
- interferes w/ interlocking of crystals as they form
- finer particle size = greater expansion
Thermal expansion
Inversion expansion of refractory
- all crystalline forms undergo sudden expansion as change a -> b form
- silica used singly or together to give desired expansion
Hygroscopic expansion: in contact w/ H2O during set
3 types of investment materials
Gypsum bonded
Phosphate bonded
Silica bonded
Composition of gypsum bonded investment
Refractory: a-hemihydrate CaSO4 (stone) 25-55%
Binder: cristobalite and/or quartz 55-75%
Additives: 2-3%
- C; reducing agent
- boric acid, NaCl; regulate set, expansion
Properties of gypsum bonded investment
35% hemihydrate, 65% cristobalite: thermal expansion 1.2% @ 700 Setting expansion: max 0.6% in air Hygroscopic expansion: 1.2-2.2% - immersed in H2O or wet liner in casting ring - continues setting reaction - promote crystal growth Cheap Sufficiently strong Porous for Au alloys Req. metal ring for support
Use of gypsum bonded investment
Gold alloys MPt up to 700
Composition of phosphate bonded investment
Refractory: formed by acid/base reaction; 20%
Binder: cristobalite and/or quartz; 80%
C: red. agent
- not for Ag-Pd alloys >1500 as causes brittleness
Properties of phosphate bonded investment
Mixed w/ H2O - thermal: 1% - setting: 0.5% Mixed w/ colloidal silica suspension - thermal: 1.3-1.6% - setting: 0.5% Hygroscopic: possible when mixed w/ colloidal silica
Stronger cf gypsum; don’t req. metal rings
Finer particle size = smooth surface cf gypsum
Set affected by temp
Use of phosphate bonded investment
Higher MPt alloys up to 1000
- gold, base metal, metal-ceramic, all ceramic
Preferred choice as can be used for all alloys up to 1200