p block (o family) Flashcards
oxygen family
oxygen
sulphur
selenium
telurium
polonium
livermorium
livermorium
extremely radioactive and synthetic,unseen
mettallic char
oxygen,sulphur are non metals
selenium and tellurium are metalloids
polonium metallic also radioactive with a very short half life
most abundant element
oxygen
role of oxygen in the weigth of earths crust and water in oxygen
earths crust-silicate minerals-46.6%
ocean water-89%
16th most abundant in earths crust
sulphur
sulphur occur as sulphates such as
gypsom CaSO4.2H2O
epsom salt MgSO4.7H2O
baryte BaSO4
sulphur occur as sulphides such as
galena
zinc blende
sopper pyrates
principle source of Se,
Te
anode mud deposited during the refining of Cu
decay prdt of thorium and uranium
polonium
ec
ns2 np4
IE
IE1 is lower than corresponding 15
IE2 is higher than corresponding 15
[ due to symmentrical and more stable ec of grp 15 ]
why electron gain enthalpy of oxygen is the least negative
bcos of its small size,electron electron replusion in the relatively 2p orbtal are high hence the incoming electrons are not accepted
most en element
oxygen
why grp 16 is less metallic
high ionisation enthalpy
insulater
sulphur
semiconductors
selinium and telurium [metalloids]
melting point and boiling point
increases doent the grp
as size increases
wan der vaals force of attraction increases
elemental state
oxygen is diatomic others are octaatomic
catenation
sulphar has more interest than oxygen becaus single bons btw sulphur is more stronger
allotropy
oxygen-dioxygen,ozone or trioxygen
sulphur has several allotropic forms
how conduction and intensity of light realted
as intensity of light increases
conduction increases
…… used for measuring the intensity of light
selenium
formation of hydride
H2E
bond angle btw hydrides
decreases down the grp
volatility order
h2s>h2se>h2te>h2o
size increases wan der waals force increases
h2o has interatomic h bonding
reactivity towards oxygen
EO2,EO3
ozone and SO2 are……… at room temp
gases
SeO2,TeO2,PoO2
crystalline ionic solids
trioxides of grp 16
acidic in nature
in the form EO3.O3
SO3 are gases