f block Flashcards

1
Q

last electron enters to(f block)?

A

[(n-2)f]

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2
Q

no.of orbitals contained by f subshell?

A

7

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3
Q

general outermost electronic configuration and its 3 valence subshells?

A

[noble gas] (n-2)f^1-14 (n-1)d^0 or1 ns^2

  • (n-2)f,(n-2)d,ns
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4
Q

why f block elements are known as inner transition elements/metals?

A

since in f block elements a transition within the transition occurs.

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5
Q

rare earth is also known as….

A

lanthanoids

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6
Q

La(57) and f block elements following it is from which grp and which period?

A

3rd group and 6th period

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7
Q

after La(57)…..third grp ki EC

A

Ce(58)………Lu(71)
……….1-14 0 or 1 2
[Xe]4f 5d 6s

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8
Q

what are actinones/actinoids?

A

14 elements coming after Ac(89)

Th(90)……………Lr(103)

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9
Q

general EC of actionoids?

A

………..1-14 0 or 1 2
[Rn] 5f 6d 7s

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10
Q

actionoids belongs to?

A

7th period and 3rd grp

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11
Q

which is the only radioactive lanthanoid?

A

Promethium (Pm) 61

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12
Q

most of the actinoids are…

A

radioactive

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13
Q

non radioactive actinoids are?

A

Th(90) , Pa(91) , U(92)

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14
Q

11 elements are known as trans uranium elements/man-made elements/synthetic elements.which are they?

A

they are actinoids. from Np(93) to Lr(103).
Np,Pu,Am,Cm,Bk,Cf,Es,Fm,Md,No,Lr.

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15
Q

ec of La

A

……….1 2
[Xe]5d 6s

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16
Q

EC of Ce(58)

A

………..1 1 2
[Xe] 4f 5d 6s

17
Q

EC of Gd(64)

A

………7 1 2
[Xe]4f 5d 6s

18
Q

who have 8 unpaired electron?

A

Gd

19
Q

Lu(71)

A

………14 1 2
[Xe]4f 5d 6s

20
Q

Tm(69)

A

thulium
……… 13 2
[Xe]4f 6s

21
Q

most abundant lanthanoid

A

Ce(58)

22
Q

who have high ionisation enthalpy among lanthanoid and actinoid?

A

lanthanoid

23
Q

magnetic moment of lanthanoids have contributions from..

A

spin magnetic moment and orbital magnetic moment

24
Q

who have the highest magnetic moment?

A

Nd(60)
[xe] 4f(4) 6s(2)

25
Q

mag.moment of Ln is contrubuted by?

A

spin mag.moment

26
Q

who have higher effective nuclear charge?why?

A

actinoids.
since nuclear-electron attraction is greater and atomic/ionic radius is smaller.e/m ratio of actinoids is higher.

27
Q

actinoids form stable complexes with…

A

EDTA , diketones, oxine and with pi acceptor acide ligands(CO)

28
Q

lanthanoid contraction

A

due to poor shielding effect of 4f (La to Lu)

29
Q

certain pair of elements( in 2nd and 3rd transition series) have similar atomic and ionic radii and so similar chemical properties and always occur together in nature

A

Zr(160pm)
Hf (159 pm)