p block Flashcards

1
Q

meta form / pyro form made by removing

A

H2O

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2
Q

hypo form is made by removing

A

oxygen

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3
Q

phosphinic acid

A

hypo phosphorus acid h3po2

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4
Q

phosphonic acid

A

ortho phosphorus acid h3po3

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5
Q

ortho means

A

normal ex h3po3 / h3po4

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6
Q

Xe03 IS PREPARED FROM HYDROLYSIS OF

A

XeF4 Xe F 6

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7
Q

Match the formulas of oxides given in Column I with the type of oxide given in
Column II and mark the correct option.
Column I Column II
(A) Pb3O4

(1) Neutral oxide
(B) N2O (2) Acidic oxide
(C) Mn2O7

(3) Basic oxide

(D) Bi2O3

(4) Mixed oxide

Code :

(i) A (1) B (2) C (3) D (4)
(ii) A (4) B (1) C (2) D (3)
(iii) A (3) B (2) C (4) D (1)
(iv) A (4) B (3) C (1) D (2)

A

B

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8
Q
In a cyclotrimetaphosphoric acid molecule, how many single and double
bonds are present?
(i) 3 double bonds; 9 single bonds
(ii) 6 double bonds; 6 single bonds
(iii) 3 double bonds; 12 single bonds
(iv) Zero double bonds; 12 single bonds
A

1

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9
Q
  1. Which of the following elements does not show allotropy?
    (i) Nitrogen
    (ii) Bismuth
    (iii) Antimony
    (iv) Arsenic
A

1

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10
Q

Which of the following statements is wrong?
(i) Single N–N bond is stronger than the single P–P bond.
(ii) PH3
can act as a ligand in the formation of coordination compound
with transition elements.
(iii) NO2
is paramagnetic in nature.
(iv) Covalency of nitrogen in N2O5
is four.

A

1

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11
Q
Elements of group-15 form compounds in +5 oxidation state. However,
bismuth forms only one well characterised compound in +5 oxidation state.
The compound is
(i) Bi2O5
(ii) BiF5
(iii) BiCl5
(iv) Bi2
S5
A

2

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12
Q

In the preparation of HNO3

, we get NO gas by catalytic oxidation of ammonia.

The moles of NO produced by the oxidation of two moles of NH3

will be ______.

(i) 2
(ii) 3
(iii) 4
(iv) 6

A

the preparation of HNO 3, we get NO gas by catalytic oxidation of ammonia. The moles of NO produced by the oxidation of two moles of NH 3 will be 2

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13
Q

A black compound of manganese reacts with a halogen acid to give greenish
yellow gas. When excess of this gas reacts with NH3

an unstable trihalide is

formed. In this process the oxidation state of nitrogen changes from _________.
(i) – 3 to +3
(ii) – 3 to 0
(iii) – 3 to +5
(iv) 0 to – 3

A

MNO2 + NACL + H2SO4 = MNCL2 + CL2 +NAHSO4 NH3 + CL2 = NCL3

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14
Q
34. Which of the following orders are correct as per the properties mentioned against
each?
(i) As2O3
< SiO2
< P2O3
< SO2

Acid strength.

(ii) AsH3
< PH3
< NH3 Enthalpy of vapourisation.

(iii) S < O < Cl < F More negative electron gain enthalpy.
(iv) H2O > H2S > H2Se > H2

Te Thermal stability.

A

1 2

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15
Q
  1. In which of the following reactions conc. H2
    SO4
    is used as an oxidising reagent?

(i) CaF2
+ H2
SO4 → CaSO4
+ 2HF

(ii) 2HI + H2SO4 → I2
\+ SO2
\+ 2H2O
(iii) Cu + 2H2SO4 → CuSO4
\+ SO2
\+ 2H2O

(iv) NaCl + H2SO4 → NaHSO4
+ HCl

A

2 3

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16
Q

back bonding effect on

A

acidic nature & h bond strength

17
Q

back bonding ^

A

acidic nature & h bond strength ^

18
Q

hydrolysis

A

+ charge ^ /polarising power ^ /covalent nature ^/ presence of vacent orbital ^

19
Q

NA CL , Mg cl2 . alcl3 , hydrolysis order

A

+ charge ^ «<

20
Q

licl ,Becl2, bCl3,CCL4 hydrolysis order

A

ccl4 ( no vacent orbital ) licl < becl2< bcl3

21
Q

down the period hydrolysis

A
22
Q

down the group hydrolysis

A

decrease ionic nature ^