p block Flashcards
meta form / pyro form made by removing
H2O
hypo form is made by removing
oxygen
phosphinic acid
hypo phosphorus acid h3po2
phosphonic acid
ortho phosphorus acid h3po3
ortho means
normal ex h3po3 / h3po4
Xe03 IS PREPARED FROM HYDROLYSIS OF
XeF4 Xe F 6
Match the formulas of oxides given in Column I with the type of oxide given in
Column II and mark the correct option.
Column I Column II
(A) Pb3O4
(1) Neutral oxide
(B) N2O (2) Acidic oxide
(C) Mn2O7
(3) Basic oxide
(D) Bi2O3
(4) Mixed oxide
Code :
(i) A (1) B (2) C (3) D (4)
(ii) A (4) B (1) C (2) D (3)
(iii) A (3) B (2) C (4) D (1)
(iv) A (4) B (3) C (1) D (2)
B
In a cyclotrimetaphosphoric acid molecule, how many single and double bonds are present? (i) 3 double bonds; 9 single bonds (ii) 6 double bonds; 6 single bonds (iii) 3 double bonds; 12 single bonds (iv) Zero double bonds; 12 single bonds
1
- Which of the following elements does not show allotropy?
(i) Nitrogen
(ii) Bismuth
(iii) Antimony
(iv) Arsenic
1
Which of the following statements is wrong?
(i) Single N–N bond is stronger than the single P–P bond.
(ii) PH3
can act as a ligand in the formation of coordination compound
with transition elements.
(iii) NO2
is paramagnetic in nature.
(iv) Covalency of nitrogen in N2O5
is four.
1
Elements of group-15 form compounds in +5 oxidation state. However, bismuth forms only one well characterised compound in +5 oxidation state. The compound is (i) Bi2O5 (ii) BiF5 (iii) BiCl5 (iv) Bi2 S5
2
In the preparation of HNO3
, we get NO gas by catalytic oxidation of ammonia.
The moles of NO produced by the oxidation of two moles of NH3
will be ______.
(i) 2
(ii) 3
(iii) 4
(iv) 6
the preparation of HNO 3, we get NO gas by catalytic oxidation of ammonia. The moles of NO produced by the oxidation of two moles of NH 3 will be 2
A black compound of manganese reacts with a halogen acid to give greenish
yellow gas. When excess of this gas reacts with NH3
an unstable trihalide is
formed. In this process the oxidation state of nitrogen changes from _________.
(i) – 3 to +3
(ii) – 3 to 0
(iii) – 3 to +5
(iv) 0 to – 3
MNO2 + NACL + H2SO4 = MNCL2 + CL2 +NAHSO4 NH3 + CL2 = NCL3
34. Which of the following orders are correct as per the properties mentioned against each? (i) As2O3 < SiO2 < P2O3 < SO2
Acid strength.
(ii) AsH3
< PH3
< NH3 Enthalpy of vapourisation.
(iii) S < O < Cl < F More negative electron gain enthalpy.
(iv) H2O > H2S > H2Se > H2
Te Thermal stability.
1 2
- In which of the following reactions conc. H2
SO4
is used as an oxidising reagent?
(i) CaF2
+ H2
SO4 → CaSO4
+ 2HF
(ii) 2HI + H2SO4 → I2 \+ SO2 \+ 2H2O (iii) Cu + 2H2SO4 → CuSO4 \+ SO2 \+ 2H2O
(iv) NaCl + H2SO4 → NaHSO4
+ HCl
2 3