coordination compound Flashcards
nh3 act as week field ligand with
fe+2 mn+2
h2o and c2o4-2 act as stroong field ligand
co+3
ni+2 with 6sfl 6wfl
outer orbitalcomplax
cr+3 with 6sfl 6wfl
inner orbital complex
oxilato act as weak field ligand
yes
john teller effect
eg orbital in octahedral complex t2g uneffected
trans effet take placein
dsp2 square planer complex
sterio iso include
geometrical and optical iso
dsp2 &octahedral
geometrical
geometrical iso possible with
unsymmetrical bi dentate ligand
ma2b2 ma2bc
2 cis and trans
mabcd
3 (2 cis 71trans)
ma4b2 & ma4bc
2 (cis 7trans)
ma3b3 geometrical isomr
2 fac & mar
m(aa)2b2 & m(aa)2bc aa=en / ox-2 /ac-2 geometrical isomer
2 cis & trans
m(aa)b2c2
3
m(ab)3 gltcinato=ab
2 cis & trans
loptical isomer
tetra hedral geometry & ocya hedral
m(ab)3
4`
m(aa)2b2 optical isomer
3
m(aa)2bc optical isomer
3