Organic topic(Ozone) Flashcards
What is the ozone layer, how does ozone act
oute edge of the stratosphere 10-40 km above the earth, small number of ozone but it is enough to absorb most UV from the earths surface
How is ozone formed
o2-> 2o.
o2 + o. -> o3
How do CFCs act
they upset the equilibrium of formation of o3 by breaking it down
What are the properties of CFCs
chlorofluorocarbons are stable, volatile, non-flammable, non-toxic and has many uses
why are CFCs so stable
strong C-H bond
when does CFC stability falter
when the CFCs enter the stratosphere the UV radiation is strong enough to break down the C-CL bonds
What is the equation of the breakdown of a CFC
CF2Cl2-> Cl. +CF2Cl
what are the propagation steps of cl. reaction with o3
cl. + o3 -> clo. + o2
clo. + o -> cl. + o2
In the reaction of cl. with o3 why is the second step important
more cl. radicals are produced which can then attack more o3 molecules continues the cycle
show the mechanism for NO reaction with o3
NO. + O3 -> NO2. + o2
NO2+ O. -> NO. + O2
what is the overall equation for the ozone reactions
o3+O -> 2o2
What are the alternatives to CFCs
HCFCS are being used while safer products are being produced
Hydrocarbons used
HCFCS break down in 10-20 years but are less harmful than CFCs
HCF does not contain cl so cannot break down radicals
What is the reaction of OH with o3
OH. + O3 -> O2H. + O2
O2H + O -> OH. +O2
What kind of bonds can absorb IR radiation
C=O, C-H, O-H