Organic Synthesis 2.5 Flashcards by Adele Schiff

Q

Primary alcohol to alkene

A

H2SO4

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Q

Alkene to primary alcohol

A

Hydration

H3PO4/H2O

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Q

Alkene to haloalkane

A

hydrogen halide

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Q

Haloalkane to nitrile

A

NaCN

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Q

Nitrile to amine

A

H2/Ni

Reduction

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Q

Haloalkane to amine

A

NH3

Ethanol

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Q

Haloalkane to primary alcohol

A

NaOH (aq)

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Q

Primary alcohol to haloalkane

A

Sodium halide

H2SO4

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Q

Primary alcohol to aldehyde

A

NaBH4/H2O

reduction

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Q

Aldehyde to primary alcohol

A

K2Cr2O7/H2SO4

Oxidation

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Q

Aldehyde to hydroxynitrile

A

NaCN/H+

Nucleophilic addition

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Q

Aldehyde to carboxylic acid

A

K2Cr2O7/H2SO4

Oxidation

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Q

Nitrile to carboxylic acid

A

H2O/HCL

Hydrolysis

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Q

Primary alcohol to ester

A

Carboxylic acid/H2SO4

Esterification

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Q

Carboxylic acid to ester

A

Esterification

Alcohol/H2SO4

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Q

Ester to carboxylic acid

A

Dilute acid hydrolysis

Q

Ester to sodium salt of carboxylic acid and alcohol

A

NaOH (aq)

Alkaline hydrolysis

Q

Carboxylic acid to acyl chloride

A

SOCL2

Q

Acyl chloride to carboxylic acid

A

H2O

Q

Acyl Chloride to ester

A

Alcohol

Q

Acyl Chloride to primary amide

A

NH3

Q

Acyl chloride to secondary amide

A

Primary amide

Q

Benzene alkylation

A

CH3Cl / AlCL3

Q

Benzene nitration

A

Nitration HNO3/H2SO4
Reduction Sn/HCL
Then Br2

Benzene bromination

Br2 / FeBr3

Benzene chlorination

CL2 / AlCl3

Benzene alkylation

CH3COCl/ ALCl3

Phenol nitration

HNO3

Phenol bromination

Br2

Phenol neutralisation

NaOH (aq)