Organic Synthesis Flashcards
What’s the reagents and conditions for alcohol to aldehyde?
Potassium dichromate, sulfuric acid, distill a primary alcohol
What’s the reagents and conditions for aldehyde to alcohol?
LiAlH4 in dry ether
Or NaBH4 in methanol and water
What’s the reagents and conditions for aldehyde to carboxylic acid?
Potassium dichromate, sulfuric acid and reflux
What’s the reagents and conditions for alcohol to ketone?
Potassium dichromate, sulfuric acid, heat secondary alcohol in a reflux kit
What’s the reagents and conditions for ketone to alcohol?
LiAlH4 in dry ether
Or NaBH4 in methanol and water
What’s the reagents and conditions for alcohol to alkene?
Concentrated sulfuric acid or phosphoric acid and heat
What’s the reagents and conditions for alkene to alcohol?
Steam, phosphoric acid catalyst, 60 atm and 300°c
What’s the reagents and conditions for alcohol to haloalkane?
Sodium halide, sulfuric acid and 20°c
What’s the reagents and conditions for haloalkane to alcohol?
Warm sodium hydroxide, water and reflux
What’s the reagents and conditions for alkane to haloalkane?
Halogen and UV light
What’s the reagents and conditions for alkene to haloalkane?
Hydrogen halide at 20°c
What’s the reagents and conditions for haloalkane to alkene?
Potassium hydroxide, ethanol and reflux
What’s the reagents and conditions for alkene to dihaloalkane?
Halogen at 20°c
What’s the reagents and conditions for alkene to diol?
Acidified potassium manganate (KMnO4) at 20°c
What’s the reagents and conditions for alkene to alkane?
Hydrogen, Nickel catalyst at 150°c