Organic synthesis Flashcards
How do you form CO2 and water from an alkane?
Complete Combustion
How do you form an alkene from an alkane?
Cracking
What is the process and conditions to form an alkane from an alkene?
Electrophillic addition
H2 gas via hydrogenation + Ni catalyst
What is the name of the process and conditions to form a halogenoalkane from an alkane?
Halogenation (Free radical substitution)
X2, UV light
Name the mechanism and conditions to form an amine from a halogenoalkane.
Nucleophillic substitution
Excess ammonia and heat
Name the mechanism and conditions to form a nitrile from a halogenoalkane
Nucleophillic substitution
KCN, Ethanol , Reflux (heat)
Name the mechanism/process and conditions to form an alcohol from a halogenoalkane
Nucleophillic substitution / hydrolysis
Warm NaOH in reflux
Name the process to form an alkene from a halogenoalkane and it’s conditions
Elimination
HOT NaOH, ethanol reflux
Name the mechanism and conditions to form a halogenoalkane from an alkene
Electrophillic addition
HX or X2
What are the conditions + reactant to form an amine from a nitrile?
Heat LiAlH4 in ether THEN dilute H2SO4
Name the mechanism and conditions to form an alcohol from an alkene
Electrophilic addition
c.H2SO4, Reflux
Name the process and conditions to form an alkene from an alcohol
Dehydration
H2O, C.H2SO4, reflux
How is alcohol formed from glucose?
Fermentation in anaerobic conditions
Name the mechanism and conditions to form alkyl hydrogen sulfates from an alkene
Electrophillic addition
Cold C.H2SO4
Name the process and conditions to form an alcohol from alkyl hydrogen sulfates
Hydrolysis
H2O, Warm