Group 7 Physical and Chemical properties Flashcards
Fluorine state and colour at room temp
Gas
Pale yellow
Chlorine state and colour at room temp
Gas
Green
Bromine state and colour at room temp
liquid
Brown with orange vapour
Iodine state and colour at room temp
Solid
Black/grey with purple vapour
Chlorine colour in solution
Colourless
Bromine colour in solution
Orange/brown
Iodine colour in solution
Dark brown/black
Trend in boiling point in group 7
Boiling point increases down the group
Halogen molecules increase in size and have more electrons
Stronger van der waals forces
Require more energy to break the intermolecular forces
Trend in electronegativity for halogens
Halogens form more electron shields between bonding pair of electrons and positive nucleus
Electrostatic attraction decreases
So electronegativity decreases
Order of oxidisation of halogens
F2
Cl2
Br2
I2
Equation for chlorine sterilising water
No UV light
Cl2 + H2O <-> HCl + HClO
Disproportionate reaction
Reduced and oxidised in same reaction
Why is the ClO ion important for sterilising
ClO ion oxidises the cell membrane of microbes, killing them
Reaction of Cl2 with cold aqueous NaOH
Cl2 + 2NaOH —> NaCl + NaClO + H2O
Why is Cl2 used to sterilise despite toxicity
Benefits outweigh risks
Concentration of chlorine is low
Chlorine and water reaction
IN UV LIGHT
2Cl2 + 2H2O —> 4HCl + O2