Organic structure and bonding Flashcards

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1
Q

s-orbitals

A
  • spherical

- lower in energy than other orbitals in the same shell

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2
Q

p-orbital

A
  • dumb-bell shape
  • nodal plane passes through nucleus
  • higher in energy than s-orbitals
  • three p-orbitals in the same shell
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3
Q

bonding in organic molecules

A

uses linear combination of atomic orbitals
- orbitals combine to form hybrid atomic orbitals (sp, sp^2, sp^3) and molecular orbitals
hybrid atomic orbital
- combination of atomic, or hybrid atomic, orbitals from different atoms

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4
Q

properties of hybrid orbitals

A
  • the more s-character in an orbital the lower the energy - increased stability of an electron in that orbital
  • holds electrons closer to the nucleus
    the bonds becomes shorter therefore stronger
  • more directional, so they have more effective bonding interactions
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