Organic structure and bonding Flashcards
1
Q
s-orbitals
A
- spherical
- lower in energy than other orbitals in the same shell
2
Q
p-orbital
A
- dumb-bell shape
- nodal plane passes through nucleus
- higher in energy than s-orbitals
- three p-orbitals in the same shell
3
Q
bonding in organic molecules
A
uses linear combination of atomic orbitals
- orbitals combine to form hybrid atomic orbitals (sp, sp^2, sp^3) and molecular orbitals
hybrid atomic orbital
- combination of atomic, or hybrid atomic, orbitals from different atoms
4
Q
properties of hybrid orbitals
A
- the more s-character in an orbital the lower the energy - increased stability of an electron in that orbital
- holds electrons closer to the nucleus
the bonds becomes shorter therefore stronger - more directional, so they have more effective bonding interactions