Intermolecular bonding Flashcards
metallic bonding
delocalised electrons
electrostatic attraction
positive metal cores
characters of metals
mostly very strong but depends on - number of electrons -packing of cation good conductors of heat and electricity in solid and liquid state malleable and ductile lustrous
intramolecular forces
hold atoms together within a molecule
intermolecular forces
attractive forces between molecules
- intermolecular forces are much weaker than intramolecular forces
four types of intermolecular forces
- ion-dipole
- hydrogen bonds
- dipole-dipole forces
- dispersion forces, Van der Waals forces/London forces
London dispersion forces
dipole induces another in the neighbouring atoms/molecules attraction between these dipoles is a weak intermolecular force
strength increases with number of electrons (size) in a molecule
dipole-dipole forces
relate to permanent molecular dipoles
- found in bonds with electronegativity difference
- molecular dipoles require a non-uniform charge distribution in 3-D
act in addition to London forces
results in higher boiling points than expected
Ion-dipole forces
electrostatics interaction between an ion and an uncharged polar molecule
strength depends on charge on ion and magnitude of the dipole
hydrogen bonding
requires an electronegative atom O, N or F delta negative (acceptor)
a S+ hydrogen atom (donor) in a polar bond usually N-H, O-H or F-H
bonding in cellulose
major component of cell walls
- polymer of glucose
- sugar chains held rigidly together by multiple Hydrogen bonds within and between chains.
- flat sheets of hydrogen-bonded chains are held together by London dispersion forces.