Intermolecular bonding Flashcards

1
Q

metallic bonding

A

delocalised electrons
electrostatic attraction
positive metal cores

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2
Q

characters of metals

A
mostly very strong but depends on 
- number of electrons 
-packing of cation
good conductors of heat and electricity in solid and liquid state 
malleable and ductile 
lustrous
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3
Q

intramolecular forces

A

hold atoms together within a molecule

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4
Q

intermolecular forces

A

attractive forces between molecules

- intermolecular forces are much weaker than intramolecular forces

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5
Q

four types of intermolecular forces

A
  • ion-dipole
  • hydrogen bonds
  • dipole-dipole forces
  • dispersion forces, Van der Waals forces/London forces
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6
Q

London dispersion forces

A

dipole induces another in the neighbouring atoms/molecules attraction between these dipoles is a weak intermolecular force
strength increases with number of electrons (size) in a molecule

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7
Q

dipole-dipole forces

A

relate to permanent molecular dipoles
- found in bonds with electronegativity difference
- molecular dipoles require a non-uniform charge distribution in 3-D
act in addition to London forces
results in higher boiling points than expected

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8
Q

Ion-dipole forces

A

electrostatics interaction between an ion and an uncharged polar molecule
strength depends on charge on ion and magnitude of the dipole

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9
Q

hydrogen bonding

A

requires an electronegative atom O, N or F delta negative (acceptor)
a S+ hydrogen atom (donor) in a polar bond usually N-H, O-H or F-H

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10
Q

bonding in cellulose

A

major component of cell walls

  • polymer of glucose
  • sugar chains held rigidly together by multiple Hydrogen bonds within and between chains.
  • flat sheets of hydrogen-bonded chains are held together by London dispersion forces.
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