Organic Mechanisms Flashcards
1
Q
electrophilic addition
A
- for alkenes to haloalkanes
- homolytic fission
- arrows are moving out of bonds
- 2 steps (1 intermediate)
2
Q
nucleophilic subsititution
A
- haloalkane
- electron pair donor arrow moves into central carbon
- arrow moves out of bond + points to haloalkane
- 1 step (no intermediate)
3
Q
electrophilic subsititution
A
- benzene / nitration / acylation
- electrophile is generated
- 2 steps (1 intermediate)
4
Q
nucleophilic addition
A
- carbonyl to alcohol / hydroxynitrile
- arrow moves out of C=O and points to O
- arrow from H- points to central C
- intermidate -> C-O- // O- points to H+ (or H from water)
- 2 steps (1 intermediate)
- is a reduction so 2[H] is used in equation