Organic Chemistry synthetic routes Flashcards

1
Q

Mechanism from Alkenes to alkanes

A

add H2 electrophilic addition with a nickel catalyst

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2
Q

Mechanism from Alkanes to haloalkanes

A

Free radical substitution with UV light and a hydrogen halide/ halogen.

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3
Q

Mechanism from Alkenes to haloalkanes

A

Electrophilic addition of hydrogen halide e.g. HBr

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4
Q

Mechanism from Alkenes to alcohols

A

electrophilic addition with acid catalyst

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5
Q

Mechanism from alcohols to alkenes

A

Dehydration

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6
Q

Mechanism from alcohols to Ketones

A

Oxidisation of a secondary alcohol by reflux. heat with K2Cr2O7 (Potassium dichromate) catalyst.

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7
Q

Mechanism from alcohols to aldehydes

A

primary alcohol oxidisation by distillation heat with K2Cr2O7 (Potassium dichromate) catalyst. or H2SO4

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8
Q

Mechanism from alkenes to polymers

A

Polymerisation

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9
Q

Mechanism from alcohols to carboxylic acids

A

Oxidisation of primary alcohol under reflux

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10
Q

Mechanism from alcohols to haloalkanes

A

Nucleophillic substitution

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11
Q

Mechanism from haloalkanes to alcohols

A

Nucleophillic substitution

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12
Q

Mechanism from aldehydes to carboxylic acids

A

Oxidisation under reflux

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13
Q

What does oxidisation through reflux do to primary alcohols?

A

It forms a carboxylic acid

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14
Q

What does oxidisation through reflux do to secondary alcohols?

A

It forms a ketone. A k2Cr2O7 catalyst is normally needed though.

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