organic chemistry- summary of mechanisms and reaction pathways Flashcards
how do you go from a alkane to haloalkane?
halogen and UV radiation
alkene to alkane?
H2 + nickel catalyst
alcohol to alkene?
concentrated H2SO4
alkene to alcohol?
steam + (phosphoric) acid catalyst
alkene to haloalkane?
hydrogen halide
haloalkane to alcohol?
aqueous NaOH under reflux
alcohol to haloalkane?
sodium halide + H2SO4
Describe free radical substitution?
mechanism involving free radicals as its reactive intermediate(usually halogen radical e.g bromination). It is a three step process (initiation, propagation, termination).
Describe electrophilic addition?
addition reaction in which C=C is broken forming two new bonds. Addition of electrophile forms first bond causing a carbocation which forms a second bond with a negative ion. Electrophile is formed from induced dipole from C=C
Describe nucleophilic substitution?
nucleophile (e.g OH-) displaces functional group