Electrons And Bonding- Electron Structure Flashcards
What are shells?
- shells are regarded as energy levels
- energy increases and shell number increases
- the shell number is called the principal quantum number, n
How many electrons maximum can be held in each shell?
-n1 holds 2
-n2 holds 8
-n3 holds 18
-n4 holds 32
It goes by the formula: 2n squared
What is an atomic orbital?
Shells are made up of atomic orbitals. An atomic orbital is a region around the nucleus that can hold up to two electrons, with opposite spins.
Describe an s-orbital
In an s-orbital the electron cloud is the shape of a sphere. It can hold 1 or 2 electrons. Each shell from n=1 contains one s-orbital. The greater the shell number, the greater the radius of its s-orbital.
Describe a p-orbital
The electron cloud is within the shape of a dumbbell sign. P orbitals can only hold 1 or 2 electrons. There are three separate p-orbitals, one at the y-axis, one at the x-axis and one diagonal.
d- and f- orbitals
- each shell from n=3 contains 5 d-orbitals
- each shell from n=4 contains 7 f-orbitals
does each new sub shell have more energy than the previous one?
yes and within a sub-shell the orbitals have the same energy.
why are orbitals of the same sub-shell occupied singly first?
this prevents any repulsion between paired electrons until there is no further orbital available.
the order of sub shells in electron configuration
1s( shell 1), 2s and 2p (shell2), 3s and 3p(shell 3), 4s(shell 4), 3d(shell 3), 4p(shell 4)
why is 4s before 3d when it is in shell 4?
because it has a lower energy level
how many electrons max does each orbital of a subshell hold?
shell 1: 1s holds 2 electrons
shell 2: 2s holds 2 electrons and 2p holds 6 electrons
shell 3: 3s holds 2 electrons, 3p holds 6 electrons and 3d holds 10 electrons
shell 4: 4s holds 2 electrons and 4p holds 6 electrons
how is the electron configuration always written?
in order of shells
What is short hand notation?
when electron configuration is done more simply in terms of the previous noble gas plus the outer electron sub shells
when d- block elements(transition metals) lose electrons…
the electrons are lost from the 4s sub shell before the 3d sub shell
what is the first ionisation energy?
the energy required to remove one electron from each atom in one mole of gaseous atoms