Organic Chemistry Intro Flashcards
state the general formula of alkanes
CnH2n+2
state the general formula of alkenes
CnH2n
state the general formula of alcohols
CnH2n+1OH
state the general formula of alkynes
CnH2n-2
state the general formula of cyclic alkanes
CnH2n
what is molecular formula? what is the molecular formula of ethane?
- actual number of atoms in a molecule or element
- ethane = C2H6
what is empirical formula? what is the empirical formula of ethane (C2H6)?
- simplest whole number ratio of atoms in a compound
- ethane (C2H6) = CH3
what is structural formula? what is the structural formula of butan-1-ol? (C4H9OH)
- arrangement of atoms in a molecule without showing all the bonds
- butan-1-ol (C4H9OH) = CH3CH2CH2CH2OH
what is skeletal formula?
- shows the bonds of the carbon skeleton only
- hydrogen and carbon atoms not shown but functional groups are
what is displayed formula?
- shows the arrangement of atoms showing all the bonds and atoms in the molecule
what is a homologous series?
- a group of compounds with the same functional group and general formula
- successive members of the same homologous series increases by CH2
what is the prefix/suffix of the alkane homologous series? give an example.
- ane, e.g. butane
what is the prefix/suffix of the branched alkane homologous series? give an example.
alkyl- -ane, e.g. methylpropane
what is the prefix/suffix of the alkene homologous series? give an example.
- ene, e.g. propene
what is the prefix/suffix of the alcohol homologous series? give an example.
- ol, e.g. ethanol
what is the prefix/suffix of the aldehyde homologous series? give an example.
-al, e.g. propanal
what is the prefix/suffix of the ketone homologous series? give an example.
-one, e.g. propanone
what is the prefix/suffix of the carboxylic acid homologous series? give an example.
- oic acid, e.g. butanoic acid
what is the prefix/suffix of the halogenoalkane homologous series? give an example.
fluoro-/chloro-/bromo-/iodo-
e.g. bromoethane
what is the prefix/suffix of the cycloalkane homologous series? give an example.
cyclo- -ane, e.g. cyclopentane
describe the process of naming molecules (nomenclature)
1) find length of stem by counting the longest continuous chain of carbons
2) make note of any alkyl groups + their prefix - if multiple write in alphabetical order
3) make note of functional group to use to find suffix/prefix
4) if more than one identical functional group or side chain present, put di/tri/tetra in front
what is a chemical mechanism? how can they be represented?
- shows the movement of an electron during a chemical reaction
- curly arrows can be used to show the movement of a pair of electrons
- they always start from the area donating the electrons and end at the area accepting the electron or to the formation of a new bond
what are structural isomers?
same molecular formula but different structural formula
state the 3 types of structural isomerism
- chain
- positional
- functional
what is chain isomerism?
same molecular formula, different arrangement of carbon skeleton
what is positional isomerism?
same molecular formula, different position of the functional group on the carbon skeleton
what is functional group isomerism?
same molecular formula, different functional group
what are stereoisomers? how do they work?
- same structural formula different arrangement of atoms in space
- e.g. E-Z isomerism
- a single bond can rotate but a double bond cannot
- the c=c bond and the atoms bonded directly to this are flat (planar) so can’t rotate and are rigid
when does E-Z isomerism occur? what does the E mean? what does the Z mean?
- when there are 2 different atoms or groups of atoms on the same carbon
- E: same groups opposite the double bond (diagonal or vertical)
- Z: same groups on the same side of the double bond
what are the Cahn - Ingold - Prelog (CIP) rules? when are they used?
- used when deciding if an isomer is E or Z when there are 4 different groups around the double bond
1) label carbons with double bond as carbon 1 and carbon 2
2) calculate the atomic (proton) number of the first element directly bonded to carbon 1 C=C. the atom with the highest atomic number is given higher priority.
3) repeat for carbon 2
4) use high priority groups to determine if E or Z
*may have to check further down the chain of priorities are the same