Organic Chemistry Flashcards

You may prefer our related Brainscape-certified flashcards:
1
Q

IUPAC Naming Steps

A
Parent chain (longest chain) 
number the chain so that the highest priority functional groups receives the lowest possible number (suffix) 
substituents with a prefix 
assign numbers to the substituents 
alphabetizing the substituents
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Alkanes

A

hydrocarbons without any double or triple bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Suffix for alkanes

A

-ane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Alkenes and alkynes and their suffixes

A

Alkenes (double bonds) and alkynes (triple bonds)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

alcohols and their suffixes and prefixes

A

OH, suffix (ol) and prefix (hydroxy)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

DIols: geminial vs. vicinial

A

diols are two hydroxyl groups
Gemini Twins: same carbon
Vicinial (vicinity): (adjacent carbons)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Aldehydes (definition, suffix, prefix)

A

carbonyl group with the CO-H on the terminal chain terminating sequence (raw hide)

Suffix: al, prefix (oxo)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Ketones (definition, suffix, prefix)

A

carbonyll gorup with the CO within the chain

Suffix: -one,
Prefix (-oxo, and -keto)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Common names of aldehydes

A

formaldehyde (methanal), acetaldehyde (ethanal), and propionaldehyde (propanal)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Common names for ketones (just how to name them)

A

naming the alkyl group on either side alphabetically and adding ketone
Example: 2-butanone is called ethylmethylketone

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

alpha carbon is what

A

carbon right next to the carbonyl

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

carboxyllic acids

A

COOH

Highest priority functional groups

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Naming Carboxyllic Acids

A

Always terminal. suffix -oic acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Common names for carboxyllic acids

A

formic acid (methanoic acid), acetic acid (ethanoic acid) and propionic acid (propanoic acid)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

esters, suffix and prefix

A

carboxyllic derivatives where the OH is replaced by the OR group

Suffix: -oate
Prefix: alkoxycarbonyl

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Amides, suffix and prefix

A

replace the hydroxyl group of a carboxylic acid with an amino group that may or may not be substituted

Suffix: -amide
Prefix: -carbamoyl or amido

Substituents attached to the amide nitrogen are designated with a capital N

17
Q

Anhydrides

A

formed from two carboxylic acids by dehydration
Can be symmetric (same acid), asymmetric (two different acids)

Suffix: anyhydrides in place of acid
If the anhydride is formed from one or more carboxyllic acid, both are named in alphabetical order in the name before the word anhydride