Organic Chemistry Flashcards
IUPAC Naming Steps
Parent chain (longest chain) number the chain so that the highest priority functional groups receives the lowest possible number (suffix) substituents with a prefix assign numbers to the substituents alphabetizing the substituents
Alkanes
hydrocarbons without any double or triple bonds
Suffix for alkanes
-ane
Alkenes and alkynes and their suffixes
Alkenes (double bonds) and alkynes (triple bonds)
alcohols and their suffixes and prefixes
OH, suffix (ol) and prefix (hydroxy)
DIols: geminial vs. vicinial
diols are two hydroxyl groups
Gemini Twins: same carbon
Vicinial (vicinity): (adjacent carbons)
Aldehydes (definition, suffix, prefix)
carbonyl group with the CO-H on the terminal chain terminating sequence (raw hide)
Suffix: al, prefix (oxo)
Ketones (definition, suffix, prefix)
carbonyll gorup with the CO within the chain
Suffix: -one,
Prefix (-oxo, and -keto)
Common names of aldehydes
formaldehyde (methanal), acetaldehyde (ethanal), and propionaldehyde (propanal)
Common names for ketones (just how to name them)
naming the alkyl group on either side alphabetically and adding ketone
Example: 2-butanone is called ethylmethylketone
alpha carbon is what
carbon right next to the carbonyl
carboxyllic acids
COOH
Highest priority functional groups
Naming Carboxyllic Acids
Always terminal. suffix -oic acid
Common names for carboxyllic acids
formic acid (methanoic acid), acetic acid (ethanoic acid) and propionic acid (propanoic acid)
esters, suffix and prefix
carboxyllic derivatives where the OH is replaced by the OR group
Suffix: -oate
Prefix: alkoxycarbonyl
Amides, suffix and prefix
replace the hydroxyl group of a carboxylic acid with an amino group that may or may not be substituted
Suffix: -amide
Prefix: -carbamoyl or amido
Substituents attached to the amide nitrogen are designated with a capital N
Anhydrides
formed from two carboxylic acids by dehydration
Can be symmetric (same acid), asymmetric (two different acids)
Suffix: anyhydrides in place of acid
If the anhydride is formed from one or more carboxyllic acid, both are named in alphabetical order in the name before the word anhydride