Organic Chemistry 2 - Polymers Flashcards
Polymer
molecule produced naturally or synthetically from monomers bonded together
Addition polymerisation
chemical reaction between monomers resulting in the formation of a polymer
Condensation polymerisation
When two monomers react in a condensation reaction, a small molecule (usually water) is produced as aby-product.
Polyester
produced through the reaction between an alcohol and a carboxylic acid functional group.
Polyamide
produced through reaction between a carboxylic acid and an amine functional group.
LDPE
Low density polyethene (produced in high temperatures and high pressures - possess many branches extending from the parent chain)
HDPE
high density polyethene (produced in low temperatures and low pressures - produce little branching)
Monomer
A small molecule from which a polymer can be made
Thermoplastic polymers
Polymers are only thermoplastics if the attractions between the long polymer chains are intermolecular forces; hydrogen bonds, dipole-dipole forces or dispersion forces.
Thermosetting polymers
decompose or burn when heated. They do not soften because the bonds between the chains are very strong. The covalent bonds between the polymer chains are called cross-links.
Elastomer Polymers
Formed when only occasional cross-links are present. The chains in these polymers can still move past each other when stretched but the cross-links return the chains to their original positions once the forces causing the stretching is released.
Co-polymers
produced by combing two or more different monomers together into one polymer.
bioplastic
Bioplastics are plastics produced from plant-based biomass. This is an alternative to fossil fuel sourced plastics.
Fossil fuel plastics
Vast majority of widely use plastics in society are produced from fossil fuels, particularly crude oil.
examples of fossil fuel plastics
HDPE/LDPE, PVC, PP and PS