Organic Chemistry 2 - Polymers Flashcards

1
Q

Polymer

A

molecule produced naturally or synthetically from monomers bonded together

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2
Q

Addition polymerisation

A

chemical reaction between monomers resulting in the formation of a polymer

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3
Q

Condensation polymerisation

A

When two monomers react in a condensation reaction, a small molecule (usually water) is produced as aby-product.

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4
Q

Polyester

A

produced through the reaction between an alcohol and a carboxylic acid functional group.

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5
Q

Polyamide

A

produced through reaction between a carboxylic acid and an amine functional group.

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6
Q

LDPE

A

Low density polyethene (produced in high temperatures and high pressures - possess many branches extending from the parent chain)

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7
Q

HDPE

A

high density polyethene (produced in low temperatures and low pressures - produce little branching)

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8
Q

Monomer

A

A small molecule from which a polymer can be made

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9
Q

Thermoplastic polymers

A

Polymers are only thermoplastics if the attractions between the long polymer chains are intermolecular forces; hydrogen bonds, dipole-dipole forces or dispersion forces.

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10
Q

Thermosetting polymers

A

decompose or burn when heated. They do not soften because the bonds between the chains are very strong. The covalent bonds between the polymer chains are called cross-links.

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11
Q

Elastomer Polymers

A

Formed when only occasional cross-links are present. The chains in these polymers can still move past each other when stretched but the cross-links return the chains to their original positions once the forces causing the stretching is released.

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12
Q

Co-polymers

A

produced by combing two or more different monomers together into one polymer.

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13
Q

bioplastic

A

Bioplastics are plastics produced from plant-based biomass. This is an alternative to fossil fuel sourced plastics.

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14
Q

Fossil fuel plastics

A

Vast majority of widely use plastics in society are produced from fossil fuels, particularly crude oil.

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15
Q

examples of fossil fuel plastics

A

HDPE/LDPE, PVC, PP and PS

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16
Q

Mechanical recycling

A

Plastics are shredded into small flakes, which are melted and crushed together to form pellets.
These pellets are then sent to manufacturers as raw materials to make new products from the same plastic.

17
Q

Chemical recycling

A

conversion of plastics back into either their constituent polymers, monomers or organic chemicals.

18
Q

Compostability

A

Compostable plastics require the high-temperature environment of an industrial composter. Microorganisms break down composable plastics in a short amount of time (at least 90% broken down).
No toxic residue or microplastics are left behind.