Organic Chemistry Flashcards

1
Q

What is an organic compound?

A

All compounds containing elements carbon and hydrogen (hydrocarbon)

Includes all molecules associated with life

10 million organic compounds (only 1.7 mill inorganic)

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1
Q

What is a hydrocarbon derivative?

A

a hydrocarbon that also includes carbs, lipids, proteins, nucleic acids, vitamins, plastics etc

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2
Q

What are some of the main differences between organic and inorganic compounds?

A

Organic
Covalent, low solubility and melting/boiling points, bad conductor, volatile, colourless, slow rate of reaction, living things’

(I.e. enzymes, protein, DNA, fuels)

Inorganic

Electro agent, ionic or covalent, high solubility and melting/boiling point, good conductor, non-volatile, coloured, fast rate of reaction, non-living things, non-biodegradable

(I.e. metals, salts, non-metals)

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3
Q

How many bonds does hydrogen, oxygen and carbon form?

A

Hydrogen - 1

Oxygen - 2

Carbon - 4

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4
Q

How do you represent a double bond and a triple bond, and what does it mean?

A

Double bond is shown by drawing two parallel lines between the atoms, or three for a triple bond.

It means that carbon is bonding with itself to satisfy it’s need for 4 covalent bonds, as it can’t get it elsewhere.

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5
Q

What is the difference between a saturated and unsaturated hydrocarbon?

A

Saturated - hydrocarbons where all carbon-to-carbon bonds are single bonds

Unsaturated - hydrocarbons containing one or more carbon-to-carbon double/triple bonds

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6
Q

How do you name an organic compound

A

Count the number of carbons, then add the prefix related to that number.

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7
Q

What are the suffixes for alkanes, Alkenes and alkynes?

A

Alkane - ane

Alkene - ene

Alkyne - yne

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8
Q

What is the difference between a alkane, alkene and alkyne?

A

Alkane - single bonds

Alkene - double bonds

Alkyne - triple bonds

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9
Q

What are the prefixes for 1-10?

A

Meth
Eth
Prop
But
Pent
Hex
Heat
Oct
Non
Dec

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10
Q

What is the Alkane general formula?

A

C(n)H(2n+2)

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11
Q

What is continuous chain alkane?

A

Carbon atoms connected in a non branching chain

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12
Q

What is a branched-chain alkane?

A

One or more branches of carbon atoms are attached to a continuous chain (isomer)

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13
Q

what is a Cycloalkanes?

A

Saturated hydrocarbon in which carbon atoms are connected to one another in a cyclic (ring)

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14
Q

What are the properties of Alkane?

A
  • insoluble in water
  • density lower than water
  • boiling point increases in carbon-chain length/ring size
  • vigorous reaction with Oxygen (produces heat and light - exothermic)
  • I.e. natural gas, petroleum, methane, ethane
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15
Q

What is an isomer?

A

A compound having the same molecular formula but different structural arrangements

As carbon increases, chances of isomers increases

Branching!

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16
Q

What is a stereoisomer?

A

Only branching on the edges!

Compounds having same molecular and structural formulas but different orientations of atoms in space

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17
Q

What is a cis isomer vs. a trans isomer?

A

Cis - occurs on same side

Trans - on opposite sides of double bonds

18
Q

What is a polymer?

A

A large molecule formed by bonding of smaller ones, takes very long to break down

I..e styrofoam, plastic bags, prosthetics etc

19
Q

How do you name an alkane?

A

Count from the nearest carbon,

20
Q

What is hydrogenation?

A

In Alkene hydrogenation, a hydrogen atom is added to each carbon atom of a double bond

Double bond = not enough hydrogen atoms

The opposite process (losing hydrogen and regaining double bond) is dehydrogenation

21
Q

How do you classify carbon atoms?

A

By the amount of carbon atoms bonded to other carbon atoms

Primary - carbon bonded to one other carbon
Secondary - carbon atom directly bonded to two other carbon atoms
Tertiary

22
Q

What are the functional groups in unsaturated hydrocarbons?

A

Carbon-carbon Double or triple bonds

23
Q

What are arenes?

A

Aromatic hydrocarbons - 6 membered carbon ring

Benzene ring - circle drawn inside, opposite sides are double bonds

24
What is the general formula for an alkene?
C(n)H(2n)
25
What is a functional group?
Group of atoms that give molecules similar properties Always have some properties and react in the same way Identity of molecule
26
What is the hydroxyl functional group?
-OH (oxygen and hydrogen) -suffix is -ol - soluble in water, higher boiling point (undergoes hydrogen bonding)
27
What are alcohols?
An organic compound in which an -OH group is bonded to a saturated carbon atom Derivative of alkane - hydrogen atom replaced by hydroxyl group
28
What is the R in R-OH
Radical - meaning the rest of the molecule
29
How do you name alcohols?
Chain name, drop -e add -ol, add word alchohol separated Number the chain to show position of -OH group - name and locate any other substituents present
30
What are polydroxys?
Alcohols that possess more than one hydroxyl group Diol - two groups Trial - three groups Final -e of parent alkane name is kept
31
What is methanol?
Simplest alcohol One carbon, one -OH Known as wood alcohol Fuel, natural gas
32
What is ethanol?
Two carbon monohydroxy alcohol Present in alcohol, vehicle fuel, yeast fermentation Oxidised in human body by liver enzymes
33
What is isopropyl and propanol
Three carbon monohydroxy alcohols Rubbing alcohol, antiseptic etc
34
What is glycerol
Three -OH groups on three different carbon atoms Biological antifreeze, beauty products, retains water Vapor, lubricative, prevents crystallisation Body produces is for fat metabolism
35
What are properties of alchohol?
Both polar/non polar - influenced by number of polar hydroxyl groups present Higher boiling and solubility points Unlimited solubility - hydrogen bonding can occur Extra energy needed to overcome alcohol-alcohol bond, hence higher boiling point
36
What is a phenol and its structure?
An organic compound in which an -OH group is attached to a carbon atom that is part of an aromatic carbon ring system
37
What is an aryl group?
An aromatic carbon ring system from which one hydrogen atom has been removed
38
What are some uses for phenols?
Antioxidants, antibacterials BHA, BHT - prevents spoilage Antioxidant - substance that oxidises itself in preference to other substances to protect them
39
What is a polyphenol?
A compound in which two or more phenol entities are present within the compounds structure Found within plant world
40
What is a Thiol?
An organic compound that is a sulfydrol group bonded to a saturated atom -SH (analogs of alcohols) -suffix -Thiol Cannot form hydrogen bonds
41
What are some characteristics of Thiols?
Strong unpleasant odor Lower boiling point Higher volatility Lower solubility in water compared to alcohols
42
How does the oxidation of two Thiol groups occur?
Each two Thiols lose hydrogen atom, thus linking two slur atoms together Forms disulphide (_S_S_) bond formation Reduction - breaking disulphides bond regenerates two Thiol molecules