Organic chemistry Flashcards

1
Q

What is a hydrocarbon

A

A molecule made up of hydrogen and carbon atoms only

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2
Q

What is an alkane

A

A hydrocarbon with the formula CxH(2x+2)

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3
Q

Why are alkanes a homologous series

A

They react in a similar way

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4
Q

Whay are alkanes saturated

A

They dont have any double bonds

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5
Q

What are the first four alkanes

A

Methane
Ethane
Propane
Butane

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6
Q

What happens to viscosity as hydrocarbon chain length increases

A

As chain length increases, Viscosity (gloopiness) increases

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7
Q

What happens to volatility as hydrocarbon chain length increases

A

Volatility decreases as hydrocarbon chain length increases

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8
Q

What happens to Flammability as hydrocarbon chain length increases

A

The longer the hydrocarbon is, the less flamable it is

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9
Q

What happens to boiling as hydrocarbon chain length increases

A

The longer the hydrocarbon is, the higher the boiling point is

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10
Q

When does complete combustion occur

A

When there is sufficient oxygen

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11
Q

What is the formula for complete combustion

A

Hydrocarbon + Water –> Caarbon dioxide + Water

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12
Q

What happens to carbon and hydrogen during conplete combustion

A

They are both oxidised

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13
Q

Is combustion endothermic or exothermic

A

Exothermic as it releases energy

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14
Q

What is crude oil

A

A fossil fuel formed by the remains of animals and plants

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15
Q

How do you get fossils fuels

A

BY drilling into the earth and extracting them

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16
Q

Where does crude oil go to get seperated into different fractions and what is the process called

A

Fractionating column in a process called fractional distillation

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17
Q

Explain how fractional distillation works

A

The column is hottest at the bottom and coolest at the top
The short chains evaporate and go to the top where it is coolest, where they then condense and can be extracted at the top of the column as liquids.
The long chains do not evaporate and stay liquid at the bottom of the column to be taken out.

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18
Q

What are some uses of crude oil (3)

A

Fuels, Polymers and Lubricants

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19
Q

What is cracking

A

Splitting up longer chain molecules into short chains so they can be more useful for things like fuels

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20
Q

What are the two types of cracking and what type of reaction is cracking

A

There is themal cracking and catalytic cracking
They are both thermal decomposition reactions

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21
Q

Explain catalytic cracking
Ensure to mention the temperature

A

Heat the long chain hydrocarbons until they are vaporised
Have some aluminium oxide ready as the catalyst
Pass the vaporised hydrocarbon along the aluminium oxide
It is done at 500 degrees

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22
Q

Explain thermal cracking
Ensure to mention the temperature and pressure

A

The crude oil is vaporised
It is then mixed with steam and heated at a high temperature and high pressure
The Hydrocarbon will crack
It is done at 750 degrees at 70 ATM

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23
Q

What is an alkene

A

A hydrocarbon with the general formula CxH2x

24
Q

Why are alkenes unsaturated

A

They are unsaturated because they have a double bond between the Carbons

25
Why are alkenes more reactive than alkanes
Their double bond can open up to make a single bond, allowing the two carbon atoms to bond with other atoms
26
What are the first 4 alkenes
Ethene, Propene, Butene, Pentene
27
How can you test for alkenes
Bromine water test Bromine water goes from orange to clear
28
When does incomplete combustion occur
When there is insufficient oxygen
29
What is the formula for incomplete combustion
Hydrocarbon + (insufficient) Oxygen --> Carbon + Carbon monoxide + Carbon dioxide
30
Why is carbon monoxide poisonous
It binds to the haemoglobin in your red blood cells so that you cant have enough oxygen to perform aerobic respiration properly so you cannot release energy to function.
31
How do alkenes typically react
With addition reactions
32
What is it called when hydrogen reacts with an alkene
Hydrogenation
33
What happens when steam reacts with an alkene
An alcohol with the functional group OH is produced
34
Compare making ethanol by fermentation versus Hydration
Fermentation: - Renewable - Only batch process - Carbon neutral - Relatively slow - Impure product Hydration: - Uses Non renewable ethene - Needs lots of energy to heat up - 100% efficient/ Pure product
35
What is a functional group
Functional groups are specific groups of atoms that are present within organic molecules and are responsible for the characteristic properties
36
What is the functional group of alcohols
OH
37
What is the general formula for alcohols
Cn H2n+1 OH
38
What are the first 4 alcohols
Methanol Ethanol Propanol Butanol
39
What are 3 properies of alcohols
The are flammable, soluble and can be oxidised
40
What are 3 uses of alcohols
Fuels In drinks Solvents
41
What is carboxylic acid's functional group
COOH
42
What are the first 4 carboxylic acids
Methanoic acid Ethanoic acid Propanoic acid Butanoic acid
43
What type of acids are carboxylic acids
Weak acids
44
When carboxylic acids dissociate and lose their hydrogen, how are the negative ions named
They all end in anoate
45
How do you make a carboxylic acid
You get an alcohol and oxidise it with an oxidising agent
46
What is the functional group of esters
COO
47
What are 2 properties of esters
Very volatile Have pleasant smells
48
What is the formula for making an ester
Carboxylic acid + Alcohol --> Ester + Water
49
What catalyst is used when making an ester
Sulfuric acid
50
When does condensation polymerisation occur
When monomers which contain different functional groups form polymer chains
51
Give an example of two monomers that would come together to form a polyester
A Dicarboxylic acid (COOH on both sides) A Diol (OH on both sides)
52
Whats a benefit of using polyesters over addition polymers
They are biodegradeable
53
What are the functional group of amino acids (there are 2)
NH2 and COOH NH2 is from amino group COOH is from carboxylic
54
What is the name of the polymer made when amino acids form
Polypeptide
55
What is a protein
One or more long chains of polypeptides
56
What are 2 uses of proteins
Enzymes as catalysts Haemoglobin transports oxygen Antibodies are a part of the immune system
57
What is the structure of DNA
Double helix structure made of2 bases