Organic chemistry Flashcards

1
Q

what is the homologous series

A

a family of similar compounds with similar chemical properties due to the presence of the same functional group

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2
Q

what is a functional group

A

group of atoms which are bonded in a specific arrangement that is responsible for the characteristic reactions of each member

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3
Q

describe cracking in the refinery

A
  1. long-chain hydrocarbon is heated to vapourise it
  2. the vapour is usually passed over a hot catalyst
  3. thermal decomposition
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4
Q

what happens when alkane is cracked

A

the number of atoms of C + H in the products is equal to the number of C + H atoms in the alkene

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5
Q

why is cracking important

A
  • makes the best use of petroleum
  • cracking always produces short- chain compounds with a Carbon- carbon double bond. This bond makes compounds reactive- makes plastics
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6
Q

what is the general formula for alkanes

A

CnH2n+2

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7
Q

what is the general formula for alkenes

A

CnH2n

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8
Q

where is heat applied

A

at the aluminium oxide

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9
Q

what is the test for alkenes

A

the gas produced was tested with bromine water. Brown to colourless

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10
Q

describe the products of alkane

A

one of the products is always alkene

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11
Q

give the homologous series

A
  1. Alkanes - C + H atoms, single bonds
  2. Alkenes - C + H plus 1 double Carbon bond
  3. Alcohols - C + H plus at least 1 O-H
  4. Carboxylic acids - H + C plus at least 1 COOH group
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12
Q

state the substances present in the process of cracking

A
  • 3-4cm depth of mineral wool soaked with a hydrocarbon oil
  • aluminium oxide catalyst
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13
Q

what is methyl

A

CH3

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14
Q

general formula for alcohol

A

CnH2n+1OH

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15
Q

general formula for carboxylic acids

A

CnH2n+1CO2H

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16
Q

why must the delivery tube be lifted out of the water the moment heating is stopped

A

water will get sucked up into the hot test tube and it might crack

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17
Q

what is cracking?

A

breaks molecules down into smaller ones

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18
Q

give the cracking of ethane

A

ethane –> ethene + hydrogen

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19
Q

what are alkanes

A
  1. the simplest family of organic compounds
  2. Hydrocarbons
  3. carbon bonds are all single bonds
  4. form a homologous series usually with the formula CnH2n+2
  5. unreactive
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20
Q

what are isomers

A

compounds with the same molecular formula but different structures

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21
Q

give the equation for the incomplete combustion of methane

A

2CH4 + 3O2 –> 2CO + 4H2O

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22
Q

what do alkanes also react with

A

chlorine in sunlight

23
Q

describe the trend of alkanes

A

first 4 alkanes are gases at room temperature. the next 12 are liquids and the rest are solids. Boiling points increase as attraction increases

24
Q

where are alkanes found

A

petroleum and natural gas

25
what can alkanes act as
fuels
26
give examples of alkanes
methane, ethane, propane, butane
27
why do branched isomers have a lower boiling point
because the branches make it hard for the molecules to get close so the attraction between them is weak and less heat is needed to overcome it
28
give the equation for the combustion of methane
CH4 + 2O2 --> CO2 + 2H2O + heat energy
29
what are addition reactions
an addition reaction turns an unsaturated alkene into a saturated compound
30
what are the bonds of the alkenes and why
- unsaturated - because they have double bonds
31
how are alkenes made
from alkanes by cracking
32
why are alkenes more reactive than alkanes
because the 2 bond can break, to add on other atoms
33
what can you use to test whether a hydrocarbon is unsaturated
bromine water. orange- colourless
34
use of paraffin
fuel for aircraft, oil stoves and lamps
35
describe the list of refinement of crude oil from bottom to top
1. bitumen 2. lubricating fraction 3. fuel oil 4. diesel oil 5. paraffin 6. naphtha 7. gasoline (fuel) 8. refinery gas
36
use of fuel oil
fuel for power stations, ships and for home heating systems
37
what happens as you go down the tower
boiling point and viscosity increases
38
how is natural gas formed
mainly methane gas and is usually found with petroleum
39
what is the minimum and maximum temperatures
400 celcius - bottom 25 celcius- top
40
use of naphtha
starting point of feedstock for many chemicals and plastics
41
which substance is very thick and heavy liquid
lubricating fraction
42
use of bitumen
road surfaces and roofs
43
how is petroleum formed
formed from remains of dead organisms that fell to the ocean floor and high pressures slowly converted them into petroleum
44
use of lubricating fraction
oil for engines and machinery, waxes and polishes
45
use of refinery gas
bottle gases for cooking and heating
46
what is an organic compound
contains carbon and usually hydrogen eg. petroleum
47
how is coal formed
the remains of vegetation that grew in ancient swamps. Pressure and heat slowly converted it to coal, over millions of years
48
use of gasoline
fuel for cars
49
which substance is a solid
bitumen
50
why is petroleum called a non-renewable source
because it will run out one day as we are using it up much faster that it can form
50
biggest sources of fossil fuels
natural gas coal petroleum
51
where does the refinement of crude oil happen and describe how
fractional distillation - carried out in a tower that is kept very hot at the base and cooler toward the top
52
what is a hydrocarbon
contain ONLY carbon and hydrogen
53