Organic chemistry Flashcards
Organic compounds
Carbon always forms 4 bonds and can be changed with the way it is arranged or by adding different substances like oxygen
Compounds with similar properties and the same general formula are referred to as the homologous series. This includes:
1) alkenes
2) alkanes
3) alcohols
Alkanes
Alkanes are a part of the homologous series that always have the same formular: CnH2n+2 ( there are 2x as many hydrogen than carbon +2)
Alkenes
All alkenes will contain at least one double carbon bond
C=C
There are said to be unsaturated and always follow the formula CnH2n (twice as many hydrogens)
Alkenes
All alkenes will contain at least one double carbon bond
C=C
There are said to be unsaturated and always follow the formula CnH2n (twice as many hydrogens)
Isomers
look at diagrams as reminder (dont test)
Addition reactions of alkenes (bromination)
When atoms are added to the double bond, a particular type of reaction occurs. This includes:
Bromination- The bromine loses its brown- orange colour and becomes colourless when it comes in contact with a double carbon bond. This can be used to test for UNSATURATION IN A MOLECULE
Addition reaction of alkenes (hydrogenation)
Hydrogenation- Adding hydrogen will make an alkane- specifically ethane, which is not useful but longer more complex alkanes can be used to make margarine
this requires a nickel catalyst/ 150C temp/ high pressure
Polymerisation
A chain of small, reactive monomers
For example
Poly(propene)- Carbon double bond, 3 hydrogens and 1 CH3
Poly (vinyl chloride)- carbon double bond, 3 hydrogen 1 chlorine
Poly (tetra-fluoroethene)- carbon double bond 4 F
(no test- when drawing polymers surround the monomer in a bracket and bonds coming out of the brackets that aren’t connected to anything and add n on the outside of the bracket)
Properties of plastics
insulators, lightweight, sometimes heat resistant, can be moulded into many shapes, does not rot
Uses of plastics
poly ethene- bottles
poly(propene)-ropes
poly (vinyl chloride)- window frames
poly (tetra fluoroethene)- non stick pans
How can you dispose plastics
Landfill- sites fill rapidly and plastics take hundreds of years to decompose
Burning- carbon dioxide and toxic fumes are released
recycling- reduced amount in landfills, uses less energy, conserves crude oil
Alcohols
Another member of the homologous series- CnH(2n+1)OH
Fermentation is used to make alcohols
glucose —> ethanol + carbon dioxide OR C6H12O3 —> 2C2H5OH + 2CO2
Conditions required- 30-35C temp with pressure and yeast to use as a catalyst
ethanol is then separated via fractional distillation and used in spirits such as vodka
Ethanol is mainly made by adding water to ethane in an addition reaction but this uses crude oil
Uses of ethanol
Alcoholic drinks
solvents- many substances dissolve in ethanol e.g perfume
Fuels
Testing for alcohol
Potassium dichromate changes from orange to green when it comes in contact with alcohol (used in the original breath analyser