organic chem terms Flashcards

1
Q

What does the term ‘Aliphatic’ refer to?

A

Organic compounds containing C chains and branches.

Aliphatic compounds are typically saturated or unsaturated hydrocarbons.

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2
Q

What characterizes ‘Aromatic’ compounds?

A

Organic compounds containing one or more benzene ring(s).

Aromatic compounds are known for their stability and unique chemical properties due to resonance.

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3
Q

Define ‘Cyclic’ in the context of organic chemistry.

A

Organic compounds containing C rings (not aromatic rings), also called alicyclic.

Cyclic compounds can be saturated or unsaturated.

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4
Q

What is a ‘Functional group’?

A

The atom or group of atoms that is responsible for most of the chemical reactions of a molecule.

Functional groups determine the properties and reactions of organic compounds.

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5
Q

What is a ‘Homologous series’?

A

A family of compounds with the same general formula and similar chemical properties. Each member differs by the addition of a CH group and there is a gradual change in physical properties.

Examples include alkanes, alkenes, and alkynes.

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6
Q

What is a ‘Hydrocarbon’?

A

Molecule containing hydrogen and carbon only.

Hydrocarbons can be aliphatic or aromatic.

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7
Q

What does ‘Organic chemistry’ study?

A

Study of compounds containing carbon.

Organic chemistry encompasses a wide variety of compounds, including those with functional groups.

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8
Q

What defines a ‘Saturated’ molecule?

A

Molecule containing no double bonds.

Saturated compounds have maximum hydrogen atoms attached to their carbon atoms.

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9
Q

What are ‘Stereoisomers’?

A

Molecules with the same molecular and structural formulae but a different spatial arrangement of atoms.

This includes geometric and optical isomers.

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10
Q

What are ‘Geometric isomers’?

A

Type of stereoisomerism: molecules which have different arrangement of groups around C=C.

Geometric isomers include cis and trans configurations.

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11
Q

Define ‘Structural isomers’.

A

Molecules with the same molecular formula but different structures.

Structural isomers can have different physical and chemical properties.

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12
Q

What are ‘Chain isomers’?

A

Type of structural isomerism: Structural isomers that differ by having a different carbon chain.

Chain isomers can vary in the length and branching of the carbon chain.

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13
Q

Define ‘Position isomers’.

A

Type of structural isomerism: Structural isomers that differ by having the functional group in a different position.

Position isomers can exhibit different reactivity and properties.

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14
Q

What are ‘Functional group isomers’?

A

Type of structural isomerism: Structural isomers that differ by having a different functional group.

Functional group isomers can have significantly different chemical behaviors.

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15
Q

What does ‘Unsaturated’ mean in organic chemistry?

A

Molecule containing double bond(s).

Unsaturated compounds include alkenes and alkynes, which can undergo addition reactions.

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16
Q

What is an addition reaction?

A

Reaction where a molecule joins to an unsaturated molecule to produce a saturated molecule

This type of reaction is common in organic chemistry, particularly with alkenes and alkynes.

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17
Q

What defines an aromatic compound?

A

Contain a substance called a benzene ring (C6H6)

Aromatic compounds are known for their stability and unique chemical properties due to resonance.

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18
Q

What is a biofuel?

A

A fuel produced from renewable biological resources

Examples include ethanol and biodiesel, derived from crops and waste materials.

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19
Q

What is bond fission?

A

Breaking a covalent bond

This process is essential in chemical reactions where bonds are formed or broken.

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20
Q

What is a carbon footprint?

A

A measure of the impact our activities have on the environment in terms of the amount of greenhouse gases we produce

It is typically expressed in equivalent tons of CO2.

21
Q

What does carbon neutral mean?

A

An activity that has no net carbon dioxide emissions to the atmosphere

This can be achieved by balancing emitted CO2 with an equivalent amount sequestered or offset.

22
Q

What is climate change?

A

Change to the Earth’s climate caused by pollutants

This includes changes in temperature, precipitation patterns, and extreme weather events.

23
Q

What is a catalyst?

A

A substance that speeds up a chemical reaction but is chemically unchanged at the end

Catalysts lower the activation energy needed for reactions to occur.

24
Q

What is complete combustion?

A

When all the elements in a combustion reaction are fully oxidised to CO2 and H2O

This process releases the maximum amount of energy from the fuel.

25
What is cracking?
Using either heat or a zeolite catalyst to break long chain alkanes into shorter chain alkanes and an alkene ## Footnote This process is important in the petroleum industry for converting heavy fractions into more useful products.
26
What does exothermic mean?
A reaction that gives out (exo) heat (thermic) ## Footnote Exothermic reactions are characterized by a temperature increase in the surroundings.
27
What are flue gases?
Gases that leave a chimney (flue) ## Footnote These gases often contain pollutants from combustion processes.
28
What are fossil fuels?
Non-renewable fuels made from the action of heat and pressure on dead plants and animals ## Footnote Examples include coal, oil, and natural gas.
29
What is a fraction in chemistry?
A group of hydrocarbons with similar boiling points ## Footnote Fractions are obtained through processes like fractional distillation.
30
What is fractional distillation?
A method of separating the hydrocarbons in crude oils by their boiling point ## Footnote This technique is widely used in the petroleum refining industry.
31
What is a free radical?
Species with an unpaired electron ## Footnote Free radicals are highly reactive and can initiate chain reactions in organic chemistry.
32
What is a functional group?
The atom or group of atoms that is responsible for most of the chemical reactions of a molecule ## Footnote Examples include hydroxyl (-OH), carboxyl (-COOH), and amino (-NH2) groups.
33
What is global dimming?
A decrease in the amount of sunlight reaching the earth's surface caused by atmospheric pollutants ## Footnote This phenomenon can influence climate and weather patterns.
34
What is global warming?
A heating effect resulting in a gradual increase in the overall temperature of the earth's atmosphere generally attributed to the greenhouse effect caused by increased levels of carbon dioxide, CFCs, and other pollutants ## Footnote This issue is central to discussions on climate change and environmental policy.
35
What is the greenhouse effect?
A warming of the atmosphere caused by greenhouse gases ## Footnote This effect is necessary for life, but excessive greenhouse gases lead to climate change.
36
What are greenhouse gases?
A gas that absorbs shortwave solar radiation and reemits it as long wave IR (heat) radiation ## Footnote Gases include CO2, hydrocarbons, CH4, H2O, CFCs.
37
What is a homologous series?
A family of compounds with the same general formula and similar chemical properties ## Footnote In a series, each member differs by the addition of a CH2 group.
38
What is a hydrocarbon?
Molecule containing hydrogen and carbon only ## Footnote Hydrocarbons can be saturated (alkanes) or unsaturated (alkenes and alkynes).
39
What is incomplete combustion?
When not all the elements in a combustion reaction are fully oxidized, e.g. C or CO is produced by combustion ## Footnote This process releases less energy and produces harmful pollutants.
40
What are intermolecular forces?
Weak forces between molecules ## Footnote These forces influence boiling points, melting points, and solubility of compounds.
41
What is the molecular formula?
Formula that gives the actual number of atoms of each element in one molecule. ## Footnote It represents the composition of a molecule in terms of the number of each type of atom present.
42
What does oxidation refer to in chemistry?
Adding oxygen to a substance, e.g. combustion. ## Footnote Oxidation involves the loss of electrons or an increase in oxidation state.
43
What is a reaction mechanism?
A series of steps in a chemical reaction. ## Footnote It details how reactants are transformed into products at a molecular level.
44
What are structural isomers?
Molecules with the same molecular formula but different structures. ## Footnote These isomers have different physical and chemical properties despite having the same number of atoms.
45
Define substitution reaction.
Reaction where an atom/group replaces another atom/group. ## Footnote This type of reaction is common in organic chemistry.
46
What does thermal mean in a chemical context?
Using heat in a process. ## Footnote Thermal processes can influence reaction rates and outcomes.
47
What are Van der Waals forces?
Electron movement in first molecule gives rise to a temporary dipole. This induces a dipole in another molecule which gives rise to a temporary attraction in adjacent molecules. ## Footnote These forces are weak intermolecular forces that play a crucial role in molecular interactions.
48
What is zeolite?
A naturally occurring aluminium silicate (clay) based compound that has a honeycomb cage-like structure. ## Footnote Zeolites are used in various applications including catalysis and ion-exchange.